百科

(3aS,4R,5S,7R,7aS)-5,7-Diazido-4-{4-[2-(4-bromomethyl-phenyl)-ethyl]-benzyloxy}-2,2-dimethyl-hexahydro-benzo[1,3]dioxole

(3aS,4R,5S,7R,7aS)-5,7-Diazido-4-{4-[2-(4-bromomethyl-phenyl)-ethyl]-benzyloxy}-2,2-dimethyl-hexahydro-benzo[1,3]dioxole

CAS号：840524-49-4

英文名：(3aS,4R,5S,7R,7aS)-5,7-Diazido-4-{4-[2-(4-bromomethyl-phenyl)-ethyl]-benzyloxy}-2,2-dimethyl-hexahydro-benzo[1,3]dioxole

分子式：C25H29BrN6O3

分子量：541.44

合成路线

2-deoxy-1,3-diazido-4-O-t-butyldimethylsilyl-5,6-di-O-acetylstreptamine

2-deoxy-1,3-diazido-4-O-t-butyldimethylsilyl-5,6-di-O-acetylstreptamine

(3aS,4R,5S,7R,7aS)-5,7-Diazido-4-{4-[2-(4-bromomethyl-phenyl)-ethyl]-benzyloxy}-2,2-dimethyl-hexahydro-benzo[1,3]dioxole

(3aS,4R,5S,7R,7aS)-5,7-Diazido-4-{4-[2-(4-bromomethyl-phenyl)-ethyl]-benzyloxy}-2,2-dimethyl-hexahydro-benzo[1,3]dioxole

2-deoxy-1,3-diazido-4-O-t-butyldimethylsilylstreptamine

2-deoxy-1,3-diazido-4-O-t-butyldimethylsilylstreptamine

(3aS,4R,5S,7R,7aS)-5,7-Diazido-4-{4-[2-(4-bromomethyl-phenyl)-ethyl]-benzyloxy}-2,2-dimethyl-hexahydro-benzo[1,3]dioxole

(3aS,4R,5S,7R,7aS)-5,7-Diazido-4-{4-[2-(4-bromomethyl-phenyl)-ethyl]-benzyloxy}-2,2-dimethyl-hexahydro-benzo[1,3]dioxole

2-deoxy-1,3-diazido-4-O-t-butyldimethylsilyl-5,6-O-isopropylidenestreptamine

2-deoxy-1,3-diazido-4-O-t-butyldimethylsilyl-5,6-O-isopropylidenestreptamine

(3aS,4R,5S,7R,7aS)-5,7-Diazido-4-{4-[2-(4-bromomethyl-phenyl)-ethyl]-benzyloxy}-2,2-dimethyl-hexahydro-benzo[1,3]dioxole

(3aS,4R,5S,7R,7aS)-5,7-Diazido-4-{4-[2-(4-bromomethyl-phenyl)-ethyl]-benzyloxy}-2,2-dimethyl-hexahydro-benzo[1,3]dioxole

上游原料

2-deoxy-1,3-diazido-4-O-t-butyldimethylsilylstreptamine 2-deoxy-1,3-diazido-4-O-t-butyldimethylsilyl-5,6-O-isopropylidenestreptamine 2-deoxy-1,3-diazido-4-O-t-butyldimethylsilyl-5,6-di-O-acetylstreptamine

下游产品

(1S,2R,3R,4S,6R)-4,6-Diazido-3-{4-[2-(4-bromomethyl-phenyl)-ethyl]-benzyloxy}-cyclohexane-1,2-diol (1S,2R,3R,4S,6R)-4,6-Diazido-3-{4-[2-(4-hydroxymethyl-phenyl)-ethyl]-benzyloxy}-cyclohexane-1,2-diol