百科

(4aR,4'R,8R,8aR)-4'-allyl-2,2-di-tert-butyl-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

(4aR,4'R,8R,8aR)-4'-allyl-2,2-di-tert-butyl-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

CAS号：844492-35-9

英文名：(4aR,4'R,8R,8aR)-4'-allyl-2,2-di-tert-butyl-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

分子式：C28H54O6Si2

分子量：542.896

合成路线

(R)-1-(Tetrahydro-pyran-2-yloxy)-pent-4-en-2-ol

(R)-1-(Tetrahydro-pyran-2-yloxy)-pent-4-en-2-ol

(4aR,4'R,8R,8aR)-4'-allyl-2,2-di-tert-butyl-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

(4aR,4'R,8R,8aR)-4'-allyl-2,2-di-tert-butyl-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

1,5-anhydro-2-deoxy-4,6-O-bis(tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabino-hex-1-enitol

1,5-anhydro-2-deoxy-4,6-O-bis(tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabino-hex-1-enitol

(4aR,4'R,8R,8aR)-4'-allyl-2,2-di-tert-butyl-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

(4aR,4'R,8R,8aR)-4'-allyl-2,2-di-tert-butyl-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

(R)-pent-4-ene-1,2-diol

(R)-pent-4-ene-1,2-diol

(4aR,8R,8aR)-2,2-Di-tert-butyl-6-phenylsulfanyl-8-triisopropylsilanyloxy-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-sila-naphthalene

(4aR,8R,8aR)-2,2-Di-tert-butyl-6-phenylsulfanyl-8-triisopropylsilanyloxy-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-sila-naphthalene

(4aR,4'R,8R,8aR)-4'-allyl-2,2-di-tert-butyl-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

(4aR,4'R,8R,8aR)-4'-allyl-2,2-di-tert-butyl-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

上游原料

(4aR,8R,8aR)-2,2-Di-tert-butyl-6-phenylsulfanyl-8-triisopropylsilanyloxy-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-sila-naphthalene 1,5-anhydro-2-deoxy-4,6-O-bis(tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabino-hex-1-enitol (R)-pent-4-ene-1,2-diol (R)-1-(Tetrahydro-pyran-2-yloxy)-pent-4-en-2-ol

下游产品

(4aR,8R,8aR)-2,2-Di-tert-butyl-6-[(R)-1-(tert-butyl-dimethyl-silanyloxymethyl)-but-3-enyloxy]-8-triisopropylsilanyloxy-hexahydro-1,3,5-trioxa-2-sila-naphthalene-6-carbonitrile