百科

(4aR,4'R,8R,8aR)-2,2-di-tert-butyl-4'-((E)-4-methoxybut-2-en-1-yl)-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

CAS号：844492-36-0

英文名：(4aR,4'R,8R,8aR)-2,2-di-tert-butyl-4'-((E)-4-methoxybut-2-en-1-yl)-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

分子式：C30H58O7Si2

分子量：586.948

合成路线

844492-26-8

(R)-5-(tert-Butyl-dimethyl-silanyloxy)-6-(tetrahydro-pyran-2-yloxy)-hex-2-yn-1-ol

844492-36-0

(4aR,4'R,8R,8aR)-2,2-di-tert-butyl-4'-((E)-4-methoxybut-2-en-1-yl)-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

844492-27-9

(E)-(R)-5-(tert-Butyl-dimethyl-silanyloxy)-6-(tetrahydro-pyran-2-yloxy)-hex-2-en-1-ol

844492-36-0

(4aR,4'R,8R,8aR)-2,2-di-tert-butyl-4'-((E)-4-methoxybut-2-en-1-yl)-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

262266-33-1

1,5-anhydro-2-deoxy-4,6-O-bis(tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabino-hex-1-enitol

844492-36-0

(4aR,4'R,8R,8aR)-2,2-di-tert-butyl-4'-((E)-4-methoxybut-2-en-1-yl)-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

844492-28-0

(E)-(R)-6-Methoxy-hex-4-ene-1,2-diol

844492-11-1

(4aR,8R,8aR)-2,2-Di-tert-butyl-6-phenylsulfanyl-8-triisopropylsilanyloxy-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-sila-naphthalene

844492-36-0

(4aR,4'R,8R,8aR)-2,2-di-tert-butyl-4'-((E)-4-methoxybut-2-en-1-yl)-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

844492-25-7

(R)-6-(Tetrahydro-pyran-2-yloxy)-hex-2-yne-1,5-diol

844492-36-0

(4aR,4'R,8R,8aR)-2,2-di-tert-butyl-4'-((E)-4-methoxybut-2-en-1-yl)-8-((triisopropylsilyl)oxy)tetrahydro-4H-spiro[pyrano[3,2-d][1,3,2]dioxasiline-6,2'-[1,3]dioxolane]

上游原料

(4aR,8R,8aR)-2,2-Di-tert-butyl-6-phenylsulfanyl-8-triisopropylsilanyloxy-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-sila-naphthalene 1,5-anhydro-2-deoxy-4,6-O-bis(tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabino-hex-1-enitol (E)-(R)-5-(tert-Butyl-dimethyl-silanyloxy)-6-(tetrahydro-pyran-2-yloxy)-hex-2-en-1-ol (R)-6-(Tetrahydro-pyran-2-yloxy)-hex-2-yne-1,5-diol (R)-5-(tert-Butyl-dimethyl-silanyloxy)-6-(tetrahydro-pyran-2-yloxy)-hex-2-yn-1-ol (E)-(R)-6-Methoxy-hex-4-ene-1,2-diol

下游产品

(4aR,8R,8aR)-2,2-Di-tert-butyl-6-[(E)-(R)-1-(tert-butyl-dimethyl-silanyloxymethyl)-5-methoxy-pent-3-enyloxy]-8-triisopropylsilanyloxy-hexahydro-1,3,5-trioxa-2-sila-naphthalene-6-carbonitrile