百科

(2R,3S,4S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-hept-6-en-1-one

(2R,3S,4S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-hept-6-en-1-one

CAS号：845734-54-5

英文名：(2R,3S,4S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-hept-6-en-1-one

分子式：C28H50O4Si

分子量：478.78

合成路线

{(2R,3R)-3-Methyl-3-[2-((R)-2,2,5,5-tetramethyl-[1,3]dioxan-4-yl)-ethyl]-oxiranyl}-methanol

{(2R,3R)-3-Methyl-3-[2-((R)-2,2,5,5-tetramethyl-[1,3]dioxan-4-yl)-ethyl]-oxiranyl}-methanol

(2R,3S,4S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-hept-6-en-1-one

(2R,3S,4S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-hept-6-en-1-one

2-[(2R,5S)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-methyl-tetrahydro-furan-2-yl]-2-methyl-propan-1-ol

2-[(2R,5S)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-methyl-tetrahydro-furan-2-yl]-2-methyl-propan-1-ol

(2R,3S,4S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-hept-6-en-1-one

(2R,3S,4S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-hept-6-en-1-one

2-[(2R,5S)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-methyl-tetrahydro-furan-2-yl]-2-methyl-propionaldehyde

2-[(2R,5S)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-methyl-tetrahydro-furan-2-yl]-2-methyl-propionaldehyde

(2R,3S,4S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-hept-6-en-1-one

(2R,3S,4S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-hept-6-en-1-one

上游原料

{(2R,3R)-3-Methyl-3-[2-((R)-2,2,5,5-tetramethyl-[1,3]dioxan-4-yl)-ethyl]-oxiranyl}-methanol 2-[(2R,5S)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-methyl-tetrahydro-furan-2-yl]-2-methyl-propan-1-ol 2-[(2R,5S)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-methyl-tetrahydro-furan-2-yl]-2-methyl-propionaldehyde

下游产品

(7E,10E)-(1S,2R,4S,5S,9S,13R)-1,5,9,12,12-Pentamethyl-2,4-bis-triethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadeca-7,10-dien-3-one (E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one