百科

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

CAS号：845734-71-6

英文名：(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

分子式：C26H50O6Si2

分子量：514.843

合成路线

{(2R,3R)-3-Methyl-3-[2-((R)-2,2,5,5-tetramethyl-[1,3]dioxan-4-yl)-ethyl]-oxiranyl}-methanol

{(2R,3R)-3-Methyl-3-[2-((R)-2,2,5,5-tetramethyl-[1,3]dioxan-4-yl)-ethyl]-oxiranyl}-methanol

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(1S,2R,3S,4S)-4-Methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-hept-6-ene-1,2,3-triol

(1S,2R,3S,4S)-4-Methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-hept-6-ene-1,2,3-triol

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-ethanol

(R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-ethanol

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

2-[(2R,5S)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-methyl-tetrahydro-furan-2-yl]-2-methyl-propionaldehyde

2-[(2R,5S)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-methyl-tetrahydro-furan-2-yl]-2-methyl-propionaldehyde

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(R)-1-[(2S,5R)-5-(2-Hydroxy-1,1-dimethyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-ethane-1,2-diol

(R)-1-[(2S,5R)-5-(2-Hydroxy-1,1-dimethyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-ethane-1,2-diol

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

2-[(2R,5S)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-methyl-tetrahydro-furan-2-yl]-2-methyl-propan-1-ol

2-[(2R,5S)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-methyl-tetrahydro-furan-2-yl]-2-methyl-propan-1-ol

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(R)-1-[(2S,5R)-2-Methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-ethane-1,2-diol

(R)-1-[(2S,5R)-2-Methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-ethane-1,2-diol

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(2R,3S,4S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-hept-6-en-1-one

(2R,3S,4S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-hept-6-en-1-one

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(1R,3S,4S)-4-Methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-1,3-bis-triethylsilanyloxy-hept-6-en-2-one

(1R,3S,4S)-4-Methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-1,3-bis-triethylsilanyloxy-hept-6-en-2-one

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(1S,2R,3S,4S)-4-Methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-1,3-bis-triethylsilanyloxy-hept-6-en-2-ol

(1S,2R,3S,4S)-4-Methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-1,3-bis-triethylsilanyloxy-hept-6-en-2-ol

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

(E)-(1S,2R,4S,5S,7S,8S,9R,13R)-7,8-Dihydroxy-1,5,9,12,12-pentamethyl-2,4-bis-trimethylsilanyloxy-16-oxa-bicyclo[11.2.1]hexadec-10-en-3-one

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上游原料

(1S,2R,3S,4S)-4-Methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-hept-6-ene-1,2,3-triol {(2R,3R)-3-Methyl-3-[2-((R)-2,2,5,5-tetramethyl-[1,3]dioxan-4-yl)-ethyl]-oxiranyl}-methanol 2-[(2R,5S)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-methyl-tetrahydro-furan-2-yl]-2-methyl-propan-1-ol (R)-1-[(2S,5R)-2-Methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-ethane-1,2-diol (1S,2R,3S,4S)-4-Methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-1,3-bis-triethylsilanyloxy-hept-6-en-2-ol 2-[(2R,5S)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-methyl-tetrahydro-furan-2-yl]-2-methyl-propionaldehyde (R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-ethanol (R)-1-[(2S,5R)-5-(2-Hydroxy-1,1-dimethyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-ethane-1,2-diol (2R,3S,4S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-hept-6-en-1-one (1R,3S,4S)-4-Methyl-1-[(2S,5R)-2-methyl-5-((E)-(S)-1,1,4-trimethyl-hexa-2,5-dienyl)-tetrahydro-furan-2-yl]-1,3-bis-triethylsilanyloxy-hept-6-en-2-one

下游产品

(E)-(1R,2R,3S,6R,10R,11S,12S,14S,15S)-3,7,7,10,14-Pentamethyl-16,17-dioxa-tricyclo[10.3.1.13,6]heptadec-8-ene-1,2,11,15-tetraol (E)-3-Methyl-pent-2-enoic acid (E)-(1S,2R,3S,6R,10R,11S,12S,14S,15S)-1,2,11-trihydroxy-3,7,7,10,14-pentamethyl-16,17-dioxa-tricyclo[10.3.1.13,6]heptadec-8-en-15-yl ester (E)-3-Methyl-pent-2-enoic acid (E)-(1R,2R,3S,6R,10R,11S,12S,14S,15S)-1,2,15-trihydroxy-3,7,7,10,14-pentamethyl-16,17-dioxa-tricyclo[10.3.1.13,6]heptadec-8-en-11-yl ester