百科

1-methoxy-4-{(1R,2S)-2-methyl-1-[(1R,3S,6R,7S,8S,9S)-6,8,10-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]but-3-enyloxymethyl}benzene

CAS号：845780-48-5

英文名：1-methoxy-4-{(1R,2S)-2-methyl-1-[(1R,3S,6R,7S,8S,9S)-6,8,10-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]but-3-enyloxymethyl}benzene

分子式：C45H88O5Si3

分子量：793.434

合成路线

444105-66-2

(3R,4S,5S)-4-[(tert-butyldimethylsilanyl)oxy]-3,5-dimethyltetrahydropyran-2-one

845780-48-5

1-methoxy-4-{(1R,2S)-2-methyl-1-[(1R,3S,6R,7S,8S,9S)-6,8,10-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]but-3-enyloxymethyl}benzene

845780-55-4

(S)-2-[(2S,4S,5S)-2-(4-Methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-propionaldehyde

845780-48-5

1-methoxy-4-{(1R,2S)-2-methyl-1-[(1R,3S,6R,7S,8S,9S)-6,8,10-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]but-3-enyloxymethyl}benzene

845780-29-2

(2R)-2-[(2S,4R,5S)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl]propan-1-ol

845780-48-5

1-methoxy-4-{(1R,2S)-2-methyl-1-[(1R,3S,6R,7S,8S,9S)-6,8,10-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]but-3-enyloxymethyl}benzene

845780-32-7

(3R,4S,5S)-[4,6-bis(tert-butyldimethylsilanyloxy)-3,5-dimethyl-2-oxohexyl]phosphonic acid dimethyl ester

845780-48-5

1-methoxy-4-{(1R,2S)-2-methyl-1-[(1R,3S,6R,7S,8S,9S)-6,8,10-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]but-3-enyloxymethyl}benzene

845780-42-9

(4R)-4-benzyl-3-{(2R,3S,4R)-3-hydroxy-4-[(2S,4S,5S)-2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]-2-methylpentanoyl}-oxazolidin-2-one

845780-48-5

1-methoxy-4-{(1R,2S)-2-methyl-1-[(1R,3S,6R,7S,8S,9S)-6,8,10-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]but-3-enyloxymethyl}benzene

845780-33-8

(2S,3S,4R,8R,10R)-1,3-bis(tert-butyldimethylsilanyloxy)-10-[(2S,4R,5S)-2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]-2,4,8-trimethylundec-6-en-5-one

845780-48-5

1-methoxy-4-{(1R,2S)-2-methyl-1-[(1R,3S,6R,7S,8S,9S)-6,8,10-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]but-3-enyloxymethyl}benzene

845780-44-1

(2S,3S,4R,8S,10R)-1,3-bis(tert-butyldimethylsilanyloxy)-10-[(2S,4R,5S)-2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]-2,4,8-trimethylundecan-5-one

845780-48-5

1-methoxy-4-{(1R,2S)-2-methyl-1-[(1R,3S,6R,7S,8S,9S)-6,8,10-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]but-3-enyloxymethyl}benzene

845780-45-2

(2S,3S,4S,5R,8S,10R)-1,3-bis(tert-butyldimethylsilanyloxy)-10-[(2S,4R,5S)-2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]-2,4,8-trimethylundecan-5-ol

845780-48-5

1-methoxy-4-{(1R,2S)-2-methyl-1-[(1R,3S,6R,7S,8S,9S)-6,8,10-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]but-3-enyloxymethyl}benzene

845780-46-3

(2S,4R,5S)-2-(4-methoxyphenyl)-5-methyl-4-[(1R,3S,6R,7S,8S,9S)-6,8,10-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]-[1,3]dioxane

845780-48-5

1-methoxy-4-{(1R,2S)-2-methyl-1-[(1R,3S,6R,7S,8S,9S)-6,8,10-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]but-3-enyloxymethyl}benzene

845780-34-9

(2S,3R,4R,6S,9R,10S,11S,12S)-9,11,13-tris(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4,6,10,12-pentamethyltridecan-1-ol

845780-48-5

1-methoxy-4-{(1R,2S)-2-methyl-1-[(1R,3S,6R,7S,8S,9S)-6,8,10-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]but-3-enyloxymethyl}benzene

上游原料

(S)-2-[(2S,4S,5S)-2-(4-Methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-propionaldehyde (2S,3S,4S,5R,8S,10R)-1,3-bis(tert-butyldimethylsilanyloxy)-10-[(2S,4R,5S)-2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]-2,4,8-trimethylundecan-5-ol (2R,3R,4R)-4-[(2S,4S,5S)-2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]-2-methylpentane-1,3-diol (2S,4R,5S)-2-(4-methoxyphenyl)-5-methyl-4-[(1R,3S,6R,7S,8S,9S)-6,8,10-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]-[1,3]dioxane (2R,4R)-4-[(2S,4R,5S)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl]-2-methylpentan-1-ol (4R,5S)-4-{(1S)-1-[(2S,4S,5S)-2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]ethyl}-5-methyl[1,3]dioxane-2-thione (2S,3S,4R,8S,10R)-1,3-bis(tert-butyldimethylsilanyloxy)-10-[(2S,4R,5S)-2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]-2,4,8-trimethylundecan-5-one (2S,3R,4R,6S,9R,10S,11S,12S)-9,11,13-tris(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4,6,10,12-pentamethyltridecan-1-ol (4R)-4-benzyl-3-{(2R,3S,4R)-3-hydroxy-4-[(2S,4S,5S)-2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]-2-methylpentanoyl}-oxazolidin-2-one (3R,4S,5S)-[4,6-bis(tert-butyldimethylsilanyloxy)-3,5-dimethyl-2-oxohexyl]phosphonic acid dimethyl ester (2R)-2-[(2S,4R,5S)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl]propan-1-ol (2S,3S,4R,8R,10R)-1,3-bis(tert-butyldimethylsilanyloxy)-10-[(2S,4R,5S)-2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]-2,4,8-trimethylundec-6-en-5-one (3R,4S,5S)-4-[(tert-butyldimethylsilanyl)oxy]-3,5-dimethyltetrahydropyran-2-one

下游产品

(1R,2S)-2-methyl-1-[(1R,3S,6R,7S,8S,9S)-6,8,10-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]but-3-enyl-(2R,3S,5S)-3,5-bis(tert-butyldimethylsilanyloxy)-2-methylhept-6-enoate (Z)-(3R,4S,6S,9S,10R)-4,6-bis(tert-butyldimethylsilanyloxy)-3,9-dimethyl-10-[(1R,3S,6R,7S,8S,9S)-6,8,1-tris(tert-butyldimethylsilanyloxy)-1,3,7,9-tetramethyldecyl]-3,4,5,6,9,10-hexahydro-2H-oxecin-2-one (3S,4R,5R,7S,10R,11S,12S,13S)-10,12,14-tris(tert-butyldimethylsilanyloxy)-3,5,7,11,13-pentamethyltetradec-1-en-4-ol