百科

11-oxo-13-deoxo-4'-demethyl-4'-benzyloxycarbonyl-4β-allyl-4-desoxypodophyllotoxin

11-oxo-13-deoxo-4'-demethyl-4'-benzyloxycarbonyl-4β-allyl-4-desoxypodophyllotoxin

CAS号：845863-41-4

英文名：11-oxo-13-deoxo-4'-demethyl-4'-benzyloxycarbonyl-4β-allyl-4-desoxypodophyllotoxin

分子式：C32H30O9

分子量：558.575

合成路线

4,4'-bis(tert-butyldimethylsilyl)-4'-O-demethylepipodophyllol

4,4'-bis(tert-butyldimethylsilyl)-4'-O-demethylepipodophyllol

11-oxo-13-deoxo-4'-demethyl-4'-benzyloxycarbonyl-4β-allyl-4-desoxypodophyllotoxin

11-oxo-13-deoxo-4'-demethyl-4'-benzyloxycarbonyl-4β-allyl-4-desoxypodophyllotoxin

11-oxo-13-deoxo-4'-demethylepipodophyllotoxin

11-oxo-13-deoxo-4'-demethylepipodophyllotoxin

11-oxo-13-deoxo-4'-demethyl-4'-benzyloxycarbonyl-4β-allyl-4-desoxypodophyllotoxin

11-oxo-13-deoxo-4'-demethyl-4'-benzyloxycarbonyl-4β-allyl-4-desoxypodophyllotoxin

上游原料

4,4'-bis(tert-butyldimethylsilyl)-4'-O-demethylepipodophyllol 11-oxo-13-deoxo-4'-demethylepipodophyllotoxin

下游产品

11-oxo-13-deoxo-4'-demethyl-4'-benzyloxycarbonyl-4β-(formylmethyl)-4-desoxypodophyllotoxin 11-oxo-13-deoxo-4'-demethyl-4'-benzyloxycarbonyl-4β-[2-[[2-(N',N'-dimethylamino)ethyl]amino]ethyl]-4-desoxypodophyllotoxin Carbonic acid benzyl ester 4-[(5R,5aR,8aR,9S)-9-(2,3-dihydroxy-propyl)-8-oxo-5,5a,6,8,8a,9-hexahydro-furo[3',4':6,7]naphtho[2,3-d][1,3]dioxol-5-yl]-2,6-dimethoxy-phenyl ester