百科

(1S,3R,4R,5S,6S)-4,5,6-Tris-benzyloxy-2,2-difluoro-3-prop-1-ynyl-cyclohexanol

(1S,3R,4R,5S,6S)-4,5,6-Tris-benzyloxy-2,2-difluoro-3-prop-1-ynyl-cyclohexanol

CAS号：845894-47-5

英文名：(1S,3R,4R,5S,6S)-4,5,6-Tris-benzyloxy-2,2-difluoro-3-prop-1-ynyl-cyclohexanol

分子式：C30H30F2O4

分子量：492.554

合成路线

methyl 7,7-dibromo-6,7-dideoxy-2,3,4-tri-O-benzyl-α-D-gluco-hept-6-enopyranoside

methyl 7,7-dibromo-6,7-dideoxy-2,3,4-tri-O-benzyl-α-D-gluco-hept-6-enopyranoside

(1S,3R,4R,5S,6S)-4,5,6-Tris-benzyloxy-2,2-difluoro-3-prop-1-ynyl-cyclohexanol

(1S,3R,4R,5S,6S)-4,5,6-Tris-benzyloxy-2,2-difluoro-3-prop-1-ynyl-cyclohexanol

(3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-prop-1-ynyl-tetrahydro-pyran-2-one

(3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-prop-1-ynyl-tetrahydro-pyran-2-one

(1S,3R,4R,5S,6S)-4,5,6-Tris-benzyloxy-2,2-difluoro-3-prop-1-ynyl-cyclohexanol

(1S,3R,4R,5S,6S)-4,5,6-Tris-benzyloxy-2,2-difluoro-3-prop-1-ynyl-cyclohexanol

(2S,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-methoxy-6-prop-1-ynyl-tetrahydro-pyran

(2S,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-methoxy-6-prop-1-ynyl-tetrahydro-pyran

(1S,3R,4R,5S,6S)-4,5,6-Tris-benzyloxy-2,2-difluoro-3-prop-1-ynyl-cyclohexanol

(1S,3R,4R,5S,6S)-4,5,6-Tris-benzyloxy-2,2-difluoro-3-prop-1-ynyl-cyclohexanol

Acetic acid (3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-prop-1-ynyl-tetrahydro-pyran-2-yl ester

Acetic acid (3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-prop-1-ynyl-tetrahydro-pyran-2-yl ester

(1S,3R,4R,5S,6S)-4,5,6-Tris-benzyloxy-2,2-difluoro-3-prop-1-ynyl-cyclohexanol

(1S,3R,4R,5S,6S)-4,5,6-Tris-benzyloxy-2,2-difluoro-3-prop-1-ynyl-cyclohexanol

(3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-difluoromethylene-6-prop-1-ynyl-tetrahydro-pyran

(3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-difluoromethylene-6-prop-1-ynyl-tetrahydro-pyran

(1S,3R,4R,5S,6S)-4,5,6-Tris-benzyloxy-2,2-difluoro-3-prop-1-ynyl-cyclohexanol

(1S,3R,4R,5S,6S)-4,5,6-Tris-benzyloxy-2,2-difluoro-3-prop-1-ynyl-cyclohexanol

上游原料

(2S,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-methoxy-6-prop-1-ynyl-tetrahydro-pyran (3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-prop-1-ynyl-tetrahydro-pyran-2-one (3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-difluoromethylene-6-prop-1-ynyl-tetrahydro-pyran methyl 7,7-dibromo-6,7-dideoxy-2,3,4-tri-O-benzyl-α-D-gluco-hept-6-enopyranoside Acetic acid (3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-prop-1-ynyl-tetrahydro-pyran-2-yl ester

下游产品

(1S,3R,4R,5S,6S)-4,5,6-Tris-benzyloxy-2,2-difluoro-3-hydroxymethyl-cyclohexanol