百科

(3R,4R,5R)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4-methoxy-hept-6-en-2-one

(3R,4R,5R)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4-methoxy-hept-6-en-2-one

CAS号：847845-05-0

英文名：(3R,4R,5R)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4-methoxy-hept-6-en-2-one

分子式：C21H34O4Si

分子量：378.578

合成路线

5,6-dideoxy-1,2-O-isopropylidene-3-O-methyl-alpha-D-xylo-hex-5-enofuranose

5,6-dideoxy-1,2-O-isopropylidene-3-O-methyl-alpha-D-xylo-hex-5-enofuranose

(3R,4R,5R)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4-methoxy-hept-6-en-2-one

(3R,4R,5R)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4-methoxy-hept-6-en-2-one

(3R,4S,5R)-3-Benzyloxy-4-methoxy-5-vinyl-dihydro-furan-2-one

(3R,4S,5R)-3-Benzyloxy-4-methoxy-5-vinyl-dihydro-furan-2-one

(3R,4R,5R)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4-methoxy-hept-6-en-2-one

(3R,4R,5R)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4-methoxy-hept-6-en-2-one

上游原料

5,6-dideoxy-1,2-O-isopropylidene-3-O-methyl-alpha-D-xylo-hex-5-enofuranose (3R,4S,5R)-3-Benzyloxy-4-methoxy-5-vinyl-dihydro-furan-2-one

下游产品

((1R,4S,5R)-4-benzyloxy-5-methoxy-3-methyl-cyclopent-2-enyloxy)(bromomethyl)dimethyl-silane (1R,2S,3R,4S,5S)-3-allyl-4-benzyloxy-2-hydroxymethyl-5-methoxy-3-methylcyclopentan-1-ol (1R,2R,3S,4S,5R)-2-allyl-3-benzyloxy-5-hydroxy-4-methoxy-2-methyl-cyclopentane-1-carboxylic acid methyl ester ((1R,4S,5R)-4-benzyloxy-5-methoxy-3-methyl-cyclopent-2-enyloxy)(tert-butyl)dimethylsilane (3R,4S,5R)-5-allyl-4-benzyloxy-2-hydroxy-3-methoxy-5-methyl-cyclopent-1-ene-1-carboxylic acid methyl ester (1R,4S,5R)-4-benzyloxy-5-methoxy-3-methyl-cyclopent-2-enol [(1S,2R,3S,4R,5R)-2-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-dimethyl-silanyloxymethyl)-5-methoxy-2-methyl-cyclopentyloxymethyl]-benzene (3aR,4R,5S,6R,6aR)-4-Allyl-5-benzyloxy-6-methoxy-2,2,4-trimethyl-hexahydro-1-oxa-2-sila-pentalene