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((6a'R,7'S,9a'S,Z)-7'-(hydroxymethyl)-5-methyl-3',6',6a',7',9',9a'-hexahydrodispiro[[1,3]dioxane-2,2'-cyclopenta[b]oxocine-8',2''-[1,3]dithiolan]-5-yl)methyl benzoate

((6a'R,7'S,9a'S,Z)-7'-(hydroxymethyl)-5-methyl-3',6',6a',7',9',9a'-hexahydrodispiro[[1,3]dioxane-2,2'-cyclopenta[b]oxocine-8',2''-[1,3]dithiolan]-5-yl)methyl benzoate

CAS号：84786-86-7

英文名：((6a'R,7'S,9a'S,Z)-7'-(hydroxymethyl)-5-methyl-3',6',6a',7',9',9a'-hexahydrodispiro[[1,3]dioxane-2,2'-cyclopenta[b]oxocine-8',2''-[1,3]dithiolan]-5-yl)methyl benzoate

分子式：C25H32O6S2

分子量：492.648

合成路线

(3aR,4S,6aS)-4-(((tert-butyldiphenylsilyl)oxy)methyl)tetrahydrospiro[cyclopenta[b]furan-5,2'-[1,3]dithiolan]-2(3H)-one

(3aR,4S,6aS)-4-(((tert-butyldiphenylsilyl)oxy)methyl)tetrahydrospiro[cyclopenta[b]furan-5,2'-[1,3]dithiolan]-2(3H)-one

((6a'R,7'S,9a'S,Z)-7'-(hydroxymethyl)-5-methyl-3',6',6a',7',9',9a'-hexahydrodispiro[[1,3]dioxane-2,2'-cyclopenta[b]oxocine-8',2''-[1,3]dithiolan]-5-yl)methyl benzoate

((6a'R,7'S,9a'S,Z)-7'-(hydroxymethyl)-5-methyl-3',6',6a',7',9',9a'-hexahydrodispiro[[1,3]dioxane-2,2'-cyclopenta[b]oxocine-8',2''-[1,3]dithiolan]-5-yl)methyl benzoate

(3aR,4S,6aS)-4-(((tert-butyldiphenylsilyl)oxy)methyl)hexahydrospiro[cyclopenta[b]furan-5,2'-[1,3]dithiolan]-2-ol

(3aR,4S,6aS)-4-(((tert-butyldiphenylsilyl)oxy)methyl)hexahydrospiro[cyclopenta[b]furan-5,2'-[1,3]dithiolan]-2-ol

((6a'R,7'S,9a'S,Z)-7'-(hydroxymethyl)-5-methyl-3',6',6a',7',9',9a'-hexahydrodispiro[[1,3]dioxane-2,2'-cyclopenta[b]oxocine-8',2''-[1,3]dithiolan]-5-yl)methyl benzoate

((6a'R,7'S,9a'S,Z)-7'-(hydroxymethyl)-5-methyl-3',6',6a',7',9',9a'-hexahydrodispiro[[1,3]dioxane-2,2'-cyclopenta[b]oxocine-8',2''-[1,3]dithiolan]-5-yl)methyl benzoate

1-(2-iodoethyl)-4-methyl-2,6,7-trioxabicyclo<2.2.2>octane

1-(2-iodoethyl)-4-methyl-2,6,7-trioxabicyclo<2.2.2>octane

((6a'R,7'S,9a'S,Z)-7'-(hydroxymethyl)-5-methyl-3',6',6a',7',9',9a'-hexahydrodispiro[[1,3]dioxane-2,2'-cyclopenta[b]oxocine-8',2''-[1,3]dithiolan]-5-yl)methyl benzoate

((6a'R,7'S,9a'S,Z)-7'-(hydroxymethyl)-5-methyl-3',6',6a',7',9',9a'-hexahydrodispiro[[1,3]dioxane-2,2'-cyclopenta[b]oxocine-8',2''-[1,3]dithiolan]-5-yl)methyl benzoate

84786-85-6

((6a'R,7'S,9a'S,Z)-7'-(hydroxymethyl)-5-methyl-3',6',6a',7',9',9a'-hexahydrodispiro[[1,3]dioxane-2,2'-cyclopenta[b]oxocine-8',2''-[1,3]dithiolan]-5-yl)methyl benzoate

((6a'R,7'S,9a'S,Z)-7'-(hydroxymethyl)-5-methyl-3',6',6a',7',9',9a'-hexahydrodispiro[[1,3]dioxane-2,2'-cyclopenta[b]oxocine-8',2''-[1,3]dithiolan]-5-yl)methyl benzoate

(7S,8R,9S)-9-(tert-Butyl-diphenyl-silanyloxymethyl)-8-[(Z)-4-(4-methyl-2,6,7-trioxa-bicyclo[2.2.2]oct-1-yl)-but-2-enyl]-1,4-dithia-spiro[4.4]nonan-7-ol

(7S,8R,9S)-9-(tert-Butyl-diphenyl-silanyloxymethyl)-8-[(Z)-4-(4-methyl-2,6,7-trioxa-bicyclo[2.2.2]oct-1-yl)-but-2-enyl]-1,4-dithia-spiro[4.4]nonan-7-ol

((6a'R,7'S,9a'S,Z)-7'-(hydroxymethyl)-5-methyl-3',6',6a',7',9',9a'-hexahydrodispiro[[1,3]dioxane-2,2'-cyclopenta[b]oxocine-8',2''-[1,3]dithiolan]-5-yl)methyl benzoate

((6a'R,7'S,9a'S,Z)-7'-(hydroxymethyl)-5-methyl-3',6',6a',7',9',9a'-hexahydrodispiro[[1,3]dioxane-2,2'-cyclopenta[b]oxocine-8',2''-[1,3]dithiolan]-5-yl)methyl benzoate

上游原料

(3aR,4S,6aS)-4-(((tert-butyldiphenylsilyl)oxy)methyl)hexahydrospiro[cyclopenta[b]furan-5,2'-[1,3]dithiolan]-2-ol (7S,8R,9S)-9-(tert-Butyl-diphenyl-silanyloxymethyl)-8-[(Z)-4-(4-methyl-2,6,7-trioxa-bicyclo[2.2.2]oct-1-yl)-but-2-enyl]-1,4-dithia-spiro[4.4]nonan-7-ol 1-(2-iodoethyl)-4-methyl-2,6,7-trioxabicyclo<2.2.2>octane (3aR,4S,6aS)-4-(((tert-butyldiphenylsilyl)oxy)methyl)tetrahydrospiro[cyclopenta[b]furan-5,2'-[1,3]dithiolan]-2(3H)-one

下游产品