百科

(R)-6-Methoxymethoxy-6-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-hexanoic acid ethyl ester

CAS号：848565-36-6

英文名：(R)-6-Methoxymethoxy-6-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-hexanoic acid ethyl ester

分子式：C31H58O8

分子量：558.787

合成路线

848565-35-5

4-{(R)-2-Hydroxy-2-[(2R,5R,2'R,5'R)-5'-((Z)-(R)-1-hydroxy-undec-2-enyl)-octahydro-[2,2']bifuranyl-5-yl]-ethoxymethyl}-benzoic acid methyl ester

848565-36-6

(R)-6-Methoxymethoxy-6-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-hexanoic acid ethyl ester

848565-28-6

((2R,3R,5S,6S)-3-But-3-enyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-methanol

848565-36-6

(R)-6-Methoxymethoxy-6-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-hexanoic acid ethyl ester

848565-51-5

((2R,3R,5S,6S)-3-But-3-enyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-ylmethoxy)-tert-butyl-dimethyl-silane

848565-36-6

(R)-6-Methoxymethoxy-6-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-hexanoic acid ethyl ester

848565-46-8

(S)-Methoxymethoxy-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-acetaldehyde

848565-36-6

(R)-6-Methoxymethoxy-6-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-hexanoic acid ethyl ester

848565-30-0

(R)-2-Methoxymethoxy-2-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-ethanol

848565-36-6

(R)-6-Methoxymethoxy-6-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-hexanoic acid ethyl ester

848565-45-7

4-{(R)-2-Methoxymethoxy-2-[(2R,5R,2'R,5'R)-5'-((Z)-(R)-1-methoxymethoxy-undec-2-enyl)-octahydro-[2,2']bifuranyl-5-yl]-ethoxymethyl}-benzoic acid methyl ester

848565-36-6

(R)-6-Methoxymethoxy-6-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-hexanoic acid ethyl ester

848565-33-3

4-((2R,3R,5S,6S)-3-But-3-enyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-ylmethoxymethyl)-benzoic acid (2R,3R,5S,6S)-3-but-3-enyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-ylmethyl ester

848565-36-6

(R)-6-Methoxymethoxy-6-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-hexanoic acid ethyl ester

848565-44-6

4-{(2R,3R,5S,6S)-3-[(3S,4S)-6-((2R,3S,5S,6S)-3-Formyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-3,4-bis-(toluene-4-sulfonyloxy)-hexyl]-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-ylmethoxymethyl}-benzoic acid

848565-36-6

(R)-6-Methoxymethoxy-6-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-hexanoic acid ethyl ester

4-{(2R,3R,5S,6S)-3-[(3S,4S)-6-((2R,3R,5S,6S)-3-Hydroxymethyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-3,4-bis-(toluene-4-sulfonyloxy)-hexyl]-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-ylmethoxymethyl}-benzoic acid

848565-43-5

848565-36-6

(R)-6-Methoxymethoxy-6-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-hexanoic acid ethyl ester

848565-29-7

4-{(2R,3R,5S,6S)-3-[(3S,4S)-6-[(2R,3R,5S,6S)-3-((Z)-Dec-1-enyl)-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl]-3,4-bis-(toluene-4-sulfonyloxy)-hexyl]-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-ylmethoxymethyl}-benzoic acid

848565-36-6

(R)-6-Methoxymethoxy-6-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-hexanoic acid ethyl ester

上游原料

4-{(2R,3R,5S,6S)-3-[(3S,4S)-6-((2R,3R,5S,6S)-3-Hydroxymethyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-3,4-bis-(toluene-4-sulfonyloxy)-hexyl]-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-ylmethoxymethyl}-benzoic acid 4-{(2R,3R,5S,6S)-3-[(3S,4S)-6-((2R,3S,5S,6S)-3-Formyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-3,4-bis-(toluene-4-sulfonyloxy)-hexyl]-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-ylmethoxymethyl}-benzoic acid 4-{(R)-2-Hydroxy-2-[(2R,5R,2'R,5'R)-5'-((Z)-(R)-1-hydroxy-undec-2-enyl)-octahydro-[2,2']bifuranyl-5-yl]-ethoxymethyl}-benzoic acid methyl ester ((2R,3R,5S,6S)-3-But-3-enyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-ylmethoxy)-tert-butyl-dimethyl-silane 4-((2R,3R,5S,6S)-3-But-3-enyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-ylmethoxymethyl)-benzoic acid (2R,3R,5S,6S)-3-but-3-enyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-ylmethyl ester (2E,4E)-(R)-6-Methoxymethoxy-6-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-hexa-2,4-dienoic acid ethyl ester (R)-2-Methoxymethoxy-2-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-ethanol 4-{(R)-2-Methoxymethoxy-2-[(2R,5R,2'R,5'R)-5'-((Z)-(R)-1-methoxymethoxy-undec-2-enyl)-octahydro-[2,2']bifuranyl-5-yl]-ethoxymethyl}-benzoic acid methyl ester 4-{(2R,3R,5S,6S)-3-[(3S,4S)-6-[(2R,3R,5S,6S)-3-((Z)-Dec-1-enyl)-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl]-3,4-bis-(toluene-4-sulfonyloxy)-hexyl]-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-ylmethoxymethyl}-benzoic acid (S)-Methoxymethoxy-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-acetaldehyde ((2R,3R,5S,6S)-3-But-3-enyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-methanol

下游产品

(S)-3-{(2R,8R,13R)-8-Hydroxy-2,13-bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-5-methyl-5H-furan-2-one (R)-8-Methoxymethoxy-8-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-oct-1-yn-3-one