百科

(2S,3S,4S,5S,6S)-5-Azido-2-(tert-butyl-diphenyl-silanyloxymethyl)-6-methoxy-tetrahydro-pyran-3,4-diol

(2S,3S,4S,5S,6S)-5-Azido-2-(tert-butyl-diphenyl-silanyloxymethyl)-6-methoxy-tetrahydro-pyran-3,4-diol

CAS号：849222-02-2

英文名：(2S,3S,4S,5S,6S)-5-Azido-2-(tert-butyl-diphenyl-silanyloxymethyl)-6-methoxy-tetrahydro-pyran-3,4-diol

分子式：C23H31N3O5Si

分子量：457.595

合成路线

3,4,6-tri-O-acetyl-L-galactal

3,4,6-tri-O-acetyl-L-galactal

(2S,3S,4S,5S,6S)-5-Azido-2-(tert-butyl-diphenyl-silanyloxymethyl)-6-methoxy-tetrahydro-pyran-3,4-diol

(2S,3S,4S,5S,6S)-5-Azido-2-(tert-butyl-diphenyl-silanyloxymethyl)-6-methoxy-tetrahydro-pyran-3,4-diol

上游原料

3,4,6-tri-O-acetyl-L-galactal

下游产品

methyl 4-O-acetyl-2-azido-3-O-(2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-mannopyranosyl)-6-O-tert-butyldiphenylsilyl-2-deoxy-β-L-galactopyranoside methyl 4-O-acetyl-2-azido-3-O-(2-azido-3-O-benzyl-2-deoxy-β-D-mannopyranosyl)-6-O-tert-butyldiphenylsilyl-2-deoxy-β-L-galactopyranoside methyl 4-O-acetyl-2-azido-6-O-tert-butyldiphenylsilyl-2-deoxy-β-L-galactopyranoside methyl 2-acetamido-4-O-acetyl-3-O-{2-acetamido-3-O-benzyl-4-O-(2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl)-6-O-tert-butyldimethylsilyl-2-deoxy-β-D-mannopyranosyl}-6-O-tert-butyldiphenylsilyl-2-deoxy-β-L-galactopyranoside methyl 4-O-acetyl-2-azido-3-O-{2-azido-3-O-benzyl-4-O-(3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-6-O-tert-butyldimethylsilyl-2-deoxy-β-D-mannopyranosyl}-6-O-tert-butyldiphenylsilyl-2-deoxy-β-L-galactopyranoside