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11-(tert-butyl-dimethyl-silanyloxy)-7-[1-(tert-butyl-dimethyl-silanyloxy)-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-9,19-dien-3-yn-5-one
CAS号:849361-89-3
英文名:11-(tert-butyl-dimethyl-silanyloxy)-7-[1-(tert-butyl-dimethyl-silanyloxy)-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-9,19-dien-3-yn-5-one
分子式:C42H68O6Si2
分子量:725.157
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合成路线
676474-16-1
2,2-dimethyl-propionic acid 6-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-8-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-octa-2,7-dienyl ester
849361-89-3
11-(tert-butyl-dimethyl-silanyloxy)-7-[1-(tert-butyl-dimethyl-silanyloxy)-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-9,19-dien-3-yn-5-one
676473-77-1
2,2-dimethyl-propionic acid 6-hydroxy-5-(4-methoxy-benzyloxy)-8-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-octa-2,7-dienyl ester
849361-89-3
11-(tert-butyl-dimethyl-silanyloxy)-7-[1-(tert-butyl-dimethyl-silanyloxy)-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-9,19-dien-3-yn-5-one
676474-12-7
5-(2,2-dimethyl-[1,3]dioxolan-4-yl)-5-(4-methoxy-benzyloxy)-pent-2-enoic acid methyl ester
849361-89-3
11-(tert-butyl-dimethyl-silanyloxy)-7-[1-(tert-butyl-dimethyl-silanyloxy)-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-9,19-dien-3-yn-5-one
849361-62-2
6-(2,2-dimethyl-propionyloxy)-2-(4-methoxy-benzyloxy)-hex-4-enoic acid
849361-89-3
11-(tert-butyl-dimethyl-silanyloxy)-7-[1-(tert-butyl-dimethyl-silanyloxy)-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-9,19-dien-3-yn-5-one
849361-63-3
[(E)-(S)-7-Hydroxy-3-(4-methoxy-benzyloxy)-2-oxo-hept-5-enyl]-phosphonic acid dimethyl ester
849361-89-3
11-(tert-butyl-dimethyl-silanyloxy)-7-[1-(tert-butyl-dimethyl-silanyloxy)-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-9,19-dien-3-yn-5-one
849361-61-1
2,2-dimethyl-propionic acid 5-(4-methoxy-benzyloxy)-6-oxo-hex-2-enyl ester
849361-89-3
11-(tert-butyl-dimethyl-silanyloxy)-7-[1-(tert-butyl-dimethyl-silanyloxy)-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-9,19-dien-3-yn-5-one
849361-77-9
(S)-7-[(2R,6R)-6-(2-Hydroxy-ethyl)-3,6-dihydro-2H-pyran-2-yl]-2,6-dimethyl-heptane-2,3-diol
849361-89-3
11-(tert-butyl-dimethyl-silanyloxy)-7-[1-(tert-butyl-dimethyl-silanyloxy)-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-9,19-dien-3-yn-5-one
676474-11-6
Acetic acid (S)-4-methyl-2-methylene-5-((2R,6R)-6-prop-2-ynyl-3,6-dihydro-2H-pyran-2-yl)-pentyl ester
849361-89-3
11-(tert-butyl-dimethyl-silanyloxy)-7-[1-(tert-butyl-dimethyl-silanyloxy)-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-9,19-dien-3-yn-5-one
676473-61-3
2-(2,6-dimethyl-hept-5-enyl)-6-methoxy-3,6-dihydro-2H-pyran
849361-89-3
11-(tert-butyl-dimethyl-silanyloxy)-7-[1-(tert-butyl-dimethyl-silanyloxy)-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-9,19-dien-3-yn-5-one
676474-09-2
ER-805619
849361-89-3
11-(tert-butyl-dimethyl-silanyloxy)-7-[1-(tert-butyl-dimethyl-silanyloxy)-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-9,19-dien-3-yn-5-one
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上游原料
(S)-7-[(2R,6R)-6-(2-Hydroxy-ethyl)-3,6-dihydro-2H-pyran-2-yl]-2,6-dimethyl-heptane-2,3-diol
5-(2,2-dimethyl-[1,3]dioxolan-4-yl)-5-(4-methoxy-benzyloxy)-pent-2-enoic acid methyl ester
2-{(2R,6R)-6-[(S)-4-(3,3-Dimethyl-oxiranyl)-2-methyl-butyl]-5,6-dihydro-2H-pyran-2-yl}-ethanol
ER-805619
(S)-5-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-4-methyl-pentanal
(S)-5-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-4-methyl-2-methylene-pentanal
2,2-dimethyl-propionic acid 6-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-8-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-octa-2,7-dienyl ester
Acetic acid (S)-4-methyl-2-methylene-5-((2R,6R)-6-prop-2-ynyl-3,6-dihydro-2H-pyran-2-yl)-pentyl ester
6-(2,2-dimethyl-propionyloxy)-2-(4-methoxy-benzyloxy)-hex-4-enoic acid
2-(2,6-dimethyl-hept-5-enyl)-6-methoxy-3,6-dihydro-2H-pyran
[(E)-(S)-7-Hydroxy-3-(4-methoxy-benzyloxy)-2-oxo-hept-5-enyl]-phosphonic acid dimethyl ester
2,2-dimethyl-propionic acid 6-hydroxy-5-(4-methoxy-benzyloxy)-8-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-octa-2,7-dienyl ester
2,2-dimethyl-propionic acid 5-(2,2-dimethyl-[1,3]dioxolan-4-yl)-5-(4-methoxy-benzyloxy)-pent-2-enyl ester
2,2-dimethyl-propionic acid 5-(4-methoxy-benzyloxy)-6-oxo-hex-2-enyl ester
下游产品
11-(tert-butyl-dimethyl-silanyloxy)-7-[1-(tert-butyl-dimethyl-silanyloxy)-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one
16,17-deoxy-laulimalide
C.15-epi des-epoxy-laulimalide
(3Z,9E)-(1R,7S,15S,17R)-7-[(E)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-triene-5,11-dione
ER-807903
ER-807901