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Benzoic acid (E)-(1R,3S,6R,7R,10R,13S,14S)-10-((R)-2-benzyloxymethoxy-butyl)-3,6,13-trimethyl-5,12-dioxo-4,11,17-trioxa-bicyclo[12.2.1]heptadec-8-en-7-yl ester

CAS号：849482-29-7

英文名：Benzoic acid (E)-(1R,3S,6R,7R,10R,13S,14S)-10-((R)-2-benzyloxymethoxy-butyl)-3,6,13-trimethyl-5,12-dioxo-4,11,17-trioxa-bicyclo[12.2.1]heptadec-8-en-7-yl ester

分子式：C36H46O9

分子量：622.745

合成路线

849482-36-6

Benzoic acid (R)-1-[(R)-1-methyl-2-((4R,5S)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-2-oxo-ethyl]-allyl ester

849482-29-7

Benzoic acid (E)-(1R,3S,6R,7R,10R,13S,14S)-10-((R)-2-benzyloxymethoxy-butyl)-3,6,13-trimethyl-5,12-dioxo-4,11,17-trioxa-bicyclo[12.2.1]heptadec-8-en-7-yl ester

849482-40-2

(S)-2-{(2S,5R)-5-[(S)-2-(tert-Butyl-dimethyl-silanyloxy)-propyl]-tetrahydro-furan-2-yl}-propionic acid (1R,3R)-3-benzyloxymethoxy-1-vinyl-pentyl ester

849482-29-7

Benzoic acid (E)-(1R,3S,6R,7R,10R,13S,14S)-10-((R)-2-benzyloxymethoxy-butyl)-3,6,13-trimethyl-5,12-dioxo-4,11,17-trioxa-bicyclo[12.2.1]heptadec-8-en-7-yl ester

479064-31-8

(S)-2-[(2S,5R)-5-((S)-2-Benzyloxy-propyl)-tetrahydro-furan-2-yl]-propionic acid methyl ester

849482-29-7

Benzoic acid (E)-(1R,3S,6R,7R,10R,13S,14S)-10-((R)-2-benzyloxymethoxy-butyl)-3,6,13-trimethyl-5,12-dioxo-4,11,17-trioxa-bicyclo[12.2.1]heptadec-8-en-7-yl ester

849482-22-0

(3R,5R)-5-Benzyloxymethoxy-hept-1-en-3-ol

849482-29-7

Benzoic acid (E)-(1R,3S,6R,7R,10R,13S,14S)-10-((R)-2-benzyloxymethoxy-butyl)-3,6,13-trimethyl-5,12-dioxo-4,11,17-trioxa-bicyclo[12.2.1]heptadec-8-en-7-yl ester

849482-37-7

(R)-3-Benzyloxymethoxy-pentanoic acid methyl ester

849482-29-7

Benzoic acid (E)-(1R,3S,6R,7R,10R,13S,14S)-10-((R)-2-benzyloxymethoxy-butyl)-3,6,13-trimethyl-5,12-dioxo-4,11,17-trioxa-bicyclo[12.2.1]heptadec-8-en-7-yl ester

479064-30-7

(E)-3-[(1S,3S)-3-Benzyloxy-1-(2-iodo-ethyl)-butoxy]-2-methyl-acrylic acid methyl ester

849482-29-7

Benzoic acid (E)-(1R,3S,6R,7R,10R,13S,14S)-10-((R)-2-benzyloxymethoxy-butyl)-3,6,13-trimethyl-5,12-dioxo-4,11,17-trioxa-bicyclo[12.2.1]heptadec-8-en-7-yl ester

上游原料

(S)-2-{(2S,5R)-5-[(S)-2-(tert-Butyl-dimethyl-silanyloxy)-propyl]-tetrahydro-furan-2-yl}-propionic acid (1R,3R)-3-benzyloxymethoxy-1-vinyl-pentyl ester (S)-2-[(2S,5R)-5-((S)-2-Benzyloxy-propyl)-tetrahydro-furan-2-yl]-propionic acid methyl ester (3R,5R)-5-Benzyloxymethoxy-hept-1-en-3-ol (E)-3-[(1S,3S)-3-Benzyloxy-1-(2-iodo-ethyl)-butoxy]-2-methyl-acrylic acid methyl ester Benzoic acid (R)-1-[(R)-1-methyl-2-((4R,5S)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-2-oxo-ethyl]-allyl ester (R)-3-Benzyloxymethoxy-pentanoic acid methyl ester

下游产品

feigrisolide C