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2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethan-1-ol

2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethan-1-ol

CAS号：849825-27-0

英文名：2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethan-1-ol

分子式：C19H32O5

分子量：340.454

合成路线

(4aR,5R,6R,8aR)-5,8a-dimethyl-5-(2-((triisopropylsilyl)oxy)ethyl)octahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]-6-carbaldehyde

(4aR,5R,6R,8aR)-5,8a-dimethyl-5-(2-((triisopropylsilyl)oxy)ethyl)octahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]-6-carbaldehyde

2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethan-1-ol

2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethan-1-ol

(4aR,5R,6S,8aR)-5,8a-dimethyl-5-(2-((triisopropylsilyl)oxy)ethyl)octahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]-6-carbaldehyde

(4aR,5R,6S,8aR)-5,8a-dimethyl-5-(2-((triisopropylsilyl)oxy)ethyl)octahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]-6-carbaldehyde

2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethan-1-ol

2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethan-1-ol

(2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethoxy)triisopropylsilane

(2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethoxy)triisopropylsilane

2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethan-1-ol

2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethan-1-ol

((4aR,5R,6R,8aR)-5,8a-dimethyl-5-(2-((triisopropylsilyl)oxy)ethyl)octahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-6-yl)methanol

((4aR,5R,6R,8aR)-5,8a-dimethyl-5-(2-((triisopropylsilyl)oxy)ethyl)octahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-6-yl)methanol

2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethan-1-ol

2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethan-1-ol

((4aR,5R,6S,8aR)-5,8a-dimethyl-5-(2-((triisopropylsilyl)oxy)ethyl)octahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-6-yl)methanol

((4aR,5R,6S,8aR)-5,8a-dimethyl-5-(2-((triisopropylsilyl)oxy)ethyl)octahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-6-yl)methanol

2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethan-1-ol

2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethan-1-ol

上游原料

(4aR,5R,6R,8aR)-5,8a-dimethyl-5-(2-((triisopropylsilyl)oxy)ethyl)octahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]-6-carbaldehyde (2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)ethoxy)triisopropylsilane ((4aR,5R,6S,8aR)-5,8a-dimethyl-5-(2-((triisopropylsilyl)oxy)ethyl)octahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-6-yl)methanol ((4aR,5R,6R,8aR)-5,8a-dimethyl-5-(2-((triisopropylsilyl)oxy)ethyl)octahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-6-yl)methanol (4aR,5R,6S,8aR)-5,8a-dimethyl-5-(2-((triisopropylsilyl)oxy)ethyl)octahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]-6-carbaldehyde

下游产品

(R)-2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)-1-(furan-3-yl)ethan-1-ol 2-((4aR,5R,6R,8aR)-6-(1,3-dioxolan-2-yl)-5,8a-dimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)acetaldehyde