百科

(R)-6-[(E)-(3R,4R,6R)-8-(Benzyl-dimethyl-silanyl)-6-(tert-butyl-dimethyl-silanyloxy)-4-(3,4-dimethoxy-benzyloxymethoxy)-3-methyl-3-triethylsilanyloxy-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

CAS号：850146-94-0

英文名：(R)-6-[(E)-(3R,4R,6R)-8-(Benzyl-dimethyl-silanyl)-6-(tert-butyl-dimethyl-silanyloxy)-4-(3,4-dimethoxy-benzyloxymethoxy)-3-methyl-3-triethylsilanyloxy-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

分子式：C45H70O8Si3

分子量：823.289

合成路线

850146-99-5

3,4-dimethoxybenzyl (methylthio)methyl ether

850146-94-0

(R)-6-[(E)-(3R,4R,6R)-8-(Benzyl-dimethyl-silanyl)-6-(tert-butyl-dimethyl-silanyloxy)-4-(3,4-dimethoxy-benzyloxymethoxy)-3-methyl-3-triethylsilanyloxy-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

850146-88-2

(R)-1-(Benzyl-dimethyl-silanyl)-6,6-diethoxy-5-hydroxy-hept-1-yn-3-one

850146-94-0

(R)-6-[(E)-(3R,4R,6R)-8-(Benzyl-dimethyl-silanyl)-6-(tert-butyl-dimethyl-silanyloxy)-4-(3,4-dimethoxy-benzyloxymethoxy)-3-methyl-3-triethylsilanyloxy-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

850146-89-3

(3R,5R)-1-(Benzyl-dimethyl-silanyl)-6,6-diethoxy-hept-1-yne-3,5-diol

850146-94-0

(R)-6-[(E)-(3R,4R,6R)-8-(Benzyl-dimethyl-silanyl)-6-(tert-butyl-dimethyl-silanyloxy)-4-(3,4-dimethoxy-benzyloxymethoxy)-3-methyl-3-triethylsilanyloxy-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

850146-90-6

(3R,5R)-7-(Benzyl-dimethyl-silanyl)-5-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-hept-6-yn-2-one

850146-94-0

(R)-6-[(E)-(3R,4R,6R)-8-(Benzyl-dimethyl-silanyl)-6-(tert-butyl-dimethyl-silanyloxy)-4-(3,4-dimethoxy-benzyloxymethoxy)-3-methyl-3-triethylsilanyloxy-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

850146-92-8

(E)-(3R,5R,6R,9R)-1-(Benzyl-dimethyl-silanyl)-3-(tert-butyl-dimethyl-silanyloxy)-5-(3,4-dimethoxy-benzyloxymethoxy)-6-methyl-9-triethylsilanyloxy-dodeca-7,11-dien-1-yn-6-ol

850146-94-0

(R)-6-[(E)-(3R,4R,6R)-8-(Benzyl-dimethyl-silanyl)-6-(tert-butyl-dimethyl-silanyloxy)-4-(3,4-dimethoxy-benzyloxymethoxy)-3-methyl-3-triethylsilanyloxy-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

850146-97-3

(E)-(4R,7R,8R,10R)-12-(Benzyl-dimethyl-silanyl)-10-(tert-butyl-dimethyl-silanyloxy)-8-(3,4-dimethoxy-benzyloxymethoxy)-7-methyl-dodeca-1,5-dien-11-yne-4,7-diol

850146-94-0

(R)-6-[(E)-(3R,4R,6R)-8-(Benzyl-dimethyl-silanyl)-6-(tert-butyl-dimethyl-silanyloxy)-4-(3,4-dimethoxy-benzyloxymethoxy)-3-methyl-3-triethylsilanyloxy-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

850146-93-9

Acrylic acid (E)-(1R,4R,5R,7R)-1-allyl-9-(benzyl-dimethyl-silanyl)-7-(tert-butyl-dimethyl-silanyloxy)-5-(3,4-dimethoxy-benzyloxymethoxy)-4-methyl-4-triethylsilanyloxy-non-2-en-8-ynyl ester

850146-94-0

(R)-6-[(E)-(3R,4R,6R)-8-(Benzyl-dimethyl-silanyl)-6-(tert-butyl-dimethyl-silanyloxy)-4-(3,4-dimethoxy-benzyloxymethoxy)-3-methyl-3-triethylsilanyloxy-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

上游原料

(3R,5R)-7-(Benzyl-dimethyl-silanyl)-5-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-hept-6-yn-2-one (E)-(3R,5R,6R,9R)-1-(Benzyl-dimethyl-silanyl)-3-(tert-butyl-dimethyl-silanyloxy)-5-(3,4-dimethoxy-benzyloxymethoxy)-6-methyl-9-triethylsilanyloxy-dodeca-7,11-dien-1-yn-6-ol (E)-(4R,7R,8R,10R)-12-(Benzyl-dimethyl-silanyl)-10-(tert-butyl-dimethyl-silanyloxy)-8-(3,4-dimethoxy-benzyloxymethoxy)-7-methyl-dodeca-1,5-dien-11-yne-4,7-diol (R)-1-(Benzyl-dimethyl-silanyl)-6,6-diethoxy-5-hydroxy-hept-1-yn-3-one Acrylic acid (E)-(1R,4R,5R,7R)-1-allyl-9-(benzyl-dimethyl-silanyl)-7-(tert-butyl-dimethyl-silanyloxy)-5-(3,4-dimethoxy-benzyloxymethoxy)-4-methyl-4-triethylsilanyloxy-non-2-en-8-ynyl ester (3R,5R)-1-(Benzyl-dimethyl-silanyl)-6,6-diethoxy-hept-1-yne-3,5-diol 3,4-dimethoxybenzyl (methylthio)methyl ether

下游产品

(R)-6-[(1E,7Z)-(3R,4R,6R)-8-(Benzyl-dimethyl-silanyl)-6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-3-methyl-3-triethylsilanyloxy-octa-1,7-dienyl]-5,6-dihydro-pyran-2-one