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(S)-6-[(2S,3S,5S)-3-methyl-5-(prop-2-en-1-yl)tetrahydrofuran-2-yl]-2-methylhexanoic acid

(S)-6-[(2S,3S,5S)-3-methyl-5-(prop-2-en-1-yl)tetrahydrofuran-2-yl]-2-methylhexanoic acid

CAS号：850341-28-5

英文名：(S)-6-[(2S,3S,5S)-3-methyl-5-(prop-2-en-1-yl)tetrahydrofuran-2-yl]-2-methylhexanoic acid

分子式：C15H26O3

分子量：254.365

合成路线

(-)-4-[(5R)-allyl-(3S)-methyltetrahydrofuran-(2S)-yl]butan-1-ol

(-)-4-[(5R)-allyl-(3S)-methyltetrahydrofuran-(2S)-yl]butan-1-ol

(S)-6-[(2S,3S,5S)-3-methyl-5-(prop-2-en-1-yl)tetrahydrofuran-2-yl]-2-methylhexanoic acid

(S)-6-[(2S,3S,5S)-3-methyl-5-(prop-2-en-1-yl)tetrahydrofuran-2-yl]-2-methylhexanoic acid

methyl (S)-6-[(2S,3S,5S)-5-(3-hydroxypropyl)-3-methyltetrahydrofuran-2-yl]-2-methyl-hexanoate

methyl (S)-6-[(2S,3S,5S)-5-(3-hydroxypropyl)-3-methyltetrahydrofuran-2-yl]-2-methyl-hexanoate

(S)-6-[(2S,3S,5S)-3-methyl-5-(prop-2-en-1-yl)tetrahydrofuran-2-yl]-2-methylhexanoic acid

(S)-6-[(2S,3S,5S)-3-methyl-5-(prop-2-en-1-yl)tetrahydrofuran-2-yl]-2-methylhexanoic acid

(-)-(5S)-[4-(tert-butyldimethylsilanyloxy)butyl]-(4S)-methyldihydrofuran-2-one

(-)-(5S)-[4-(tert-butyldimethylsilanyloxy)butyl]-(4S)-methyldihydrofuran-2-one

(S)-6-[(2S,3S,5S)-3-methyl-5-(prop-2-en-1-yl)tetrahydrofuran-2-yl]-2-methylhexanoic acid

(S)-6-[(2S,3S,5S)-3-methyl-5-(prop-2-en-1-yl)tetrahydrofuran-2-yl]-2-methylhexanoic acid

(-)-(5R)-allyl-(2S)-(4-iodobutyl)-(3S)-methyltetrahydrofuran

(-)-(5R)-allyl-(2S)-(4-iodobutyl)-(3S)-methyltetrahydrofuran

(S)-6-[(2S,3S,5S)-3-methyl-5-(prop-2-en-1-yl)tetrahydrofuran-2-yl]-2-methylhexanoic acid

(S)-6-[(2S,3S,5S)-3-methyl-5-(prop-2-en-1-yl)tetrahydrofuran-2-yl]-2-methylhexanoic acid

上游原料

(-)-4-[(5R)-allyl-(3S)-methyltetrahydrofuran-(2S)-yl]butan-1-ol (-)-(5R)-allyl-(2S)-(4-iodobutyl)-(3S)-methyltetrahydrofuran (-)-(5S)-[4-(tert-butyldimethylsilanyloxy)butyl]-(4S)-methyldihydrofuran-2-one methyl (S)-6-[(2S,3S,5S)-5-(3-hydroxypropyl)-3-methyltetrahydrofuran-2-yl]-2-methyl-hexanoate

下游产品

(+)-(15S)-(tert-butyldimethylsilanyloxy)-(6S,13R,19S)-trimethyl-(9R)-propyl-8,20-dioxabicyclo[15.2.1]icosane-7,11,14-trione (+)-6-[(5R)-allyl-(3S)-methyltetrahydrofuran-(2S)-yl]-(2S)-methylhexanoic acid 3-benzylidene-(5R)-methyl-7-phenyl-(1R)-propylhept-6-ynyl ester (-)-6-[(5R)-allyl-(3S)-methyltetrahydrofuran-(2S)-yl]-(2S)-methylhexanoic acid 3-benzylidene-(5S)-methyl-7-phenyl-(1R)-propylhept-6-ynyl ester (+)-(15S)-(tert-butyldimethylsilanyloxy)-(6S,13R,19S)-trimethyl-11-methylene-(9R)-propyl-8,20-dioxabicyclo[15.2.1]icosane-7,14-dione (-)-(2S)-methyl-6-[(3S)-methyl-(5R)-(2-oxoethyl)tetrahydrofuran-(2S)-yl]hexanoic acid (5R)-methyl-3-oxo-7-phenyl-(1R)-propylhept-6-ynyl ester (-)-14-benzylidene-(15S)-hydroxy-(6S,13R,19R)-trimethyl-(9R)-propyl-8,20-dioxabicyclo[15.2.1]icosan-7,11-dione (-)-amphidinolide T4