百科

(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-[(4aS,6R,7S,9aR)-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocyclohepten-6-ylmethyl]-tetrahydro-pyran-3-ol

(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-[(4aS,6R,7S,9aR)-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocyclohepten-6-ylmethyl]-tetrahydro-pyran-3-ol

CAS号：850656-82-5

英文名：(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-[(4aS,6R,7S,9aR)-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocyclohepten-6-ylmethyl]-tetrahydro-pyran-3-ol

分子式：C38H48O8

分子量：632.783

合成路线

(4aS,6R,7S,9aR)-6-Hydroxymethyl-octahydro-1,5-dioxa-benzocyclohepten-7-ol

(4aS,6R,7S,9aR)-6-Hydroxymethyl-octahydro-1,5-dioxa-benzocyclohepten-7-ol

(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-[(4aS,6R,7S,9aR)-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocyclohepten-6-ylmethyl]-tetrahydro-pyran-3-ol

(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-[(4aS,6R,7S,9aR)-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocyclohepten-6-ylmethyl]-tetrahydro-pyran-3-ol

(4aS,6S,7S,9aR)-6-Iodomethyl-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocycloheptene

(4aS,6S,7S,9aR)-6-Iodomethyl-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocycloheptene

(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-[(4aS,6R,7S,9aR)-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocyclohepten-6-ylmethyl]-tetrahydro-pyran-3-ol

(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-[(4aS,6R,7S,9aR)-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocyclohepten-6-ylmethyl]-tetrahydro-pyran-3-ol

[(4aS,6R,7S,9aR)-7-(4-Methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocyclohepten-6-yl]-methanol

[(4aS,6R,7S,9aR)-7-(4-Methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocyclohepten-6-yl]-methanol

(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-[(4aS,6R,7S,9aR)-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocyclohepten-6-ylmethyl]-tetrahydro-pyran-3-ol

(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-[(4aS,6R,7S,9aR)-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocyclohepten-6-ylmethyl]-tetrahydro-pyran-3-ol

(4aS,6R,7S,9aR)-6-((5S,6R)-5-Benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-ylmethyl)-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocycloheptene

(4aS,6R,7S,9aR)-6-((5S,6R)-5-Benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-ylmethyl)-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocycloheptene

(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-[(4aS,6R,7S,9aR)-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocyclohepten-6-ylmethyl]-tetrahydro-pyran-3-ol

(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-[(4aS,6R,7S,9aR)-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocyclohepten-6-ylmethyl]-tetrahydro-pyran-3-ol

上游原料

[(4aS,6R,7S,9aR)-7-(4-Methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocyclohepten-6-yl]-methanol (4aS,6R,7S,9aR)-6-Hydroxymethyl-octahydro-1,5-dioxa-benzocyclohepten-7-ol (4aS,6S,7S,9aR)-6-Iodomethyl-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocycloheptene (4aS,6R,7S,9aR)-6-((5S,6R)-5-Benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-ylmethyl)-7-(4-methoxy-benzyloxy)-octahydro-1,5-dioxa-benzocycloheptene

下游产品

(4aS,6R,9aR)-6-((2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-3-triethylsilanyloxy-tetrahydro-pyran-2-ylmethyl)-7-trimethylsilanyloxy-3,4,4a,6,9,9a-hexahydro-2H-1,5-dioxa-benzocycloheptene ((4aS,5aR,6aS,8R,9S,10aR,11aS,12S,13aR)-9-Benzyloxy-8-benzyloxymethyl-11a-ethylsulfanyl-tetradecahydro-1,5,7,11-tetraoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-12-yloxy)-triisopropyl-silane (4aS,6R,8S,9aR)-6-((2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-3-triethylsilanyloxy-tetrahydro-pyran-2-ylmethyl)-8-(tert-butyl-dimethyl-silanyloxy)-hexahydro-1,5-dioxa-benzocyclohepten-7-one