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Benzoic acid (2R,3R,6S,7S,8S)-9-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,6,8-trimethyl-7-(tetrahydro-pyran-2-yloxy)-nonyl ester

Benzoic acid (2R,3R,6S,7S,8S)-9-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,6,8-trimethyl-7-(tetrahydro-pyran-2-yloxy)-nonyl ester

CAS号：851121-63-6

英文名：Benzoic acid (2R,3R,6S,7S,8S)-9-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,6,8-trimethyl-7-(tetrahydro-pyran-2-yloxy)-nonyl ester

分子式：C30H52O6Si

分子量：536.816

合成路线

(E)-(4S,5S,6S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,6-dimethyl-5-(tetrahydro-pyran-2-yloxy)-hept-2-enoic acid ethyl ester

(E)-(4S,5S,6S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,6-dimethyl-5-(tetrahydro-pyran-2-yloxy)-hept-2-enoic acid ethyl ester

Benzoic acid (2R,3R,6S,7S,8S)-9-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,6,8-trimethyl-7-(tetrahydro-pyran-2-yloxy)-nonyl ester

Benzoic acid (2R,3R,6S,7S,8S)-9-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,6,8-trimethyl-7-(tetrahydro-pyran-2-yloxy)-nonyl ester

(4S,5S,6S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,6-dimethyl-5-(tetrahydro-pyran-2-yloxy)-heptanal

(4S,5S,6S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,6-dimethyl-5-(tetrahydro-pyran-2-yloxy)-heptanal

Benzoic acid (2R,3R,6S,7S,8S)-9-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,6,8-trimethyl-7-(tetrahydro-pyran-2-yloxy)-nonyl ester

Benzoic acid (2R,3R,6S,7S,8S)-9-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,6,8-trimethyl-7-(tetrahydro-pyran-2-yloxy)-nonyl ester

(4S,5S,6S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,6-dimethyl-5-(tetrahydro-pyran-2-yloxy)-heptan-1-ol

(4S,5S,6S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,6-dimethyl-5-(tetrahydro-pyran-2-yloxy)-heptan-1-ol

Benzoic acid (2R,3R,6S,7S,8S)-9-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,6,8-trimethyl-7-(tetrahydro-pyran-2-yloxy)-nonyl ester

Benzoic acid (2R,3R,6S,7S,8S)-9-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,6,8-trimethyl-7-(tetrahydro-pyran-2-yloxy)-nonyl ester

(2R,3R,4S)-5-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-3-(tetrahydro-pyran-2-yloxy)-pentanal

(2R,3R,4S)-5-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-3-(tetrahydro-pyran-2-yloxy)-pentanal

Benzoic acid (2R,3R,6S,7S,8S)-9-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,6,8-trimethyl-7-(tetrahydro-pyran-2-yloxy)-nonyl ester

Benzoic acid (2R,3R,6S,7S,8S)-9-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,6,8-trimethyl-7-(tetrahydro-pyran-2-yloxy)-nonyl ester

tert-Butyl-[(2S,3S,4S)-2,4-dimethyl-3-(tetrahydro-pyran-2-yloxy)-hex-5-enyloxy]-dimethyl-silane

tert-Butyl-[(2S,3S,4S)-2,4-dimethyl-3-(tetrahydro-pyran-2-yloxy)-hex-5-enyloxy]-dimethyl-silane

Benzoic acid (2R,3R,6S,7S,8S)-9-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,6,8-trimethyl-7-(tetrahydro-pyran-2-yloxy)-nonyl ester

Benzoic acid (2R,3R,6S,7S,8S)-9-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,6,8-trimethyl-7-(tetrahydro-pyran-2-yloxy)-nonyl ester

上游原料

(E)-(4S,5S,6S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,6-dimethyl-5-(tetrahydro-pyran-2-yloxy)-hept-2-enoic acid ethyl ester (4S,5S,6S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,6-dimethyl-5-(tetrahydro-pyran-2-yloxy)-heptan-1-ol (2R,3R,4S)-5-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-3-(tetrahydro-pyran-2-yloxy)-pentanal tert-Butyl-[(2S,3S,4S)-2,4-dimethyl-3-(tetrahydro-pyran-2-yloxy)-hex-5-enyloxy]-dimethyl-silane (4S,5S,6S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,6-dimethyl-5-(tetrahydro-pyran-2-yloxy)-heptanal

下游产品

Benzoic acid (R)-2-[(2S,5S,6S)-5-methyl-6-((R)-1-methyl-2-oxo-ethyl)-tetrahydro-pyran-2-yl]-propyl ester Benzoic acid (R)-2-{(2S,5S,6S)-6-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-5-methyl-tetrahydro-pyran-2-yl}-propyl ester