百科

2,2,2-Trifluoro-1-((2R,4aR,6S,6aR,11aR,11bS)-6-methoxy-2-phenyl-4,4a,6,6a,8,11,11a,11b-octahydro-1,3,5-trioxa-7-aza-cyclohepta[a]naphthalen-7-yl)-ethanone

2,2,2-Trifluoro-1-((2R,4aR,6S,6aR,11aR,11bS)-6-methoxy-2-phenyl-4,4a,6,6a,8,11,11a,11b-octahydro-1,3,5-trioxa-7-aza-cyclohepta[a]naphthalen-7-yl)-ethanone

CAS号：851190-90-4

英文名：2,2,2-Trifluoro-1-((2R,4aR,6S,6aR,11aR,11bS)-6-methoxy-2-phenyl-4,4a,6,6a,8,11,11a,11b-octahydro-1,3,5-trioxa-7-aza-cyclohepta[a]naphthalen-7-yl)-ethanone

分子式：C20H22F3NO5

分子量：413.388

合成路线

N-Allyl-N-((2R,4aR,6S,7R,8R,8aS)-8-allyl-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-2,2,2-trifluoro-acetamide

N-Allyl-N-((2R,4aR,6S,7R,8R,8aS)-8-allyl-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-2,2,2-trifluoro-acetamide

2,2,2-Trifluoro-1-((2R,4aR,6S,6aR,11aR,11bS)-6-methoxy-2-phenyl-4,4a,6,6a,8,11,11a,11b-octahydro-1,3,5-trioxa-7-aza-cyclohepta[a]naphthalen-7-yl)-ethanone

2,2,2-Trifluoro-1-((2R,4aR,6S,6aR,11aR,11bS)-6-methoxy-2-phenyl-4,4a,6,6a,8,11,11a,11b-octahydro-1,3,5-trioxa-7-aza-cyclohepta[a]naphthalen-7-yl)-ethanone

methyl 4,6-O-benzylidene-3-deoxy-3-C-propenyl-α-D-arabino-hexopyranoside-2-ulose

methyl 4,6-O-benzylidene-3-deoxy-3-C-propenyl-α-D-arabino-hexopyranoside-2-ulose

2,2,2-Trifluoro-1-((2R,4aR,6S,6aR,11aR,11bS)-6-methoxy-2-phenyl-4,4a,6,6a,8,11,11a,11b-octahydro-1,3,5-trioxa-7-aza-cyclohepta[a]naphthalen-7-yl)-ethanone

2,2,2-Trifluoro-1-((2R,4aR,6S,6aR,11aR,11bS)-6-methoxy-2-phenyl-4,4a,6,6a,8,11,11a,11b-octahydro-1,3,5-trioxa-7-aza-cyclohepta[a]naphthalen-7-yl)-ethanone

Allyl-((2R,4aR,6S,7R,8R,8aS)-8-allyl-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-amine

Allyl-((2R,4aR,6S,7R,8R,8aS)-8-allyl-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-amine

2,2,2-Trifluoro-1-((2R,4aR,6S,6aR,11aR,11bS)-6-methoxy-2-phenyl-4,4a,6,6a,8,11,11a,11b-octahydro-1,3,5-trioxa-7-aza-cyclohepta[a]naphthalen-7-yl)-ethanone

2,2,2-Trifluoro-1-((2R,4aR,6S,6aR,11aR,11bS)-6-methoxy-2-phenyl-4,4a,6,6a,8,11,11a,11b-octahydro-1,3,5-trioxa-7-aza-cyclohepta[a]naphthalen-7-yl)-ethanone

上游原料

N-Allyl-N-((2R,4aR,6S,7R,8R,8aS)-8-allyl-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-2,2,2-trifluoro-acetamide Allyl-((2R,4aR,6S,7R,8R,8aS)-8-allyl-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-amine methyl 4,6-O-benzylidene-3-deoxy-3-C-propenyl-α-D-arabino-hexopyranoside-2-ulose

下游产品

2,2,2-Trifluoro-1-((1S,3R,4S,4aR,9aR)-4-hydroxy-3-hydroxymethyl-1-methoxy-octahydro-2-oxa-9-aza-benzocyclohepten-9-yl)-ethanone (2R,4aR,6S,6aR,9S,10R,11aR,11bS)-6-Methoxy-2-phenyl-decahydro-1,3,5-trioxa-7-aza-cyclohepta[a]naphthalene-9,10-diol (2R,4aR,6S,6aR,11aR,11bS)-6-Methoxy-2-phenyl-4a,6,6a,7,8,11,11a,11b-octahydro-4H-1,3,5-trioxa-7-aza-cyclohepta[a]naphthalene 1-((2R,4aR,6S,6aR,9S,10R,11aR,11bS)-9,10-Dihydroxy-6-methoxy-2-phenyl-decahydro-1,3,5-trioxa-7-aza-cyclohepta[a]naphthalen-7-yl)-2,2,2-trifluoro-ethanone