百科

(E)-(2R,3R,4aS,9R,14aS)-2,3-Dimethoxy-2,3,9-trimethyl-2,3,4a,9,10,11,12,13,14,14a-decahydro-1,4,8-trioxa-benzocyclododecen-7-one

(E)-(2R,3R,4aS,9R,14aS)-2,3-Dimethoxy-2,3,9-trimethyl-2,3,4a,9,10,11,12,13,14,14a-decahydro-1,4,8-trioxa-benzocyclododecen-7-one

CAS号：851515-14-5

英文名：(E)-(2R,3R,4aS,9R,14aS)-2,3-Dimethoxy-2,3,9-trimethyl-2,3,4a,9,10,11,12,13,14,14a-decahydro-1,4,8-trioxa-benzocyclododecen-7-one

分子式：C18H30O6

分子量：342.427

合成路线

methyl (E)-3-{(2S,3S,5R,6R)-3-[(R)-6-hydroxyheptyl]-5,6-dimethoxy-5,6-dimethyl-1,4-dioxan-2-yl}acrylate

methyl (E)-3-{(2S,3S,5R,6R)-3-[(R)-6-hydroxyheptyl]-5,6-dimethoxy-5,6-dimethyl-1,4-dioxan-2-yl}acrylate

(E)-(2R,3R,4aS,9R,14aS)-2,3-Dimethoxy-2,3,9-trimethyl-2,3,4a,9,10,11,12,13,14,14a-decahydro-1,4,8-trioxa-benzocyclododecen-7-one

(E)-(2R,3R,4aS,9R,14aS)-2,3-Dimethoxy-2,3,9-trimethyl-2,3,4a,9,10,11,12,13,14,14a-decahydro-1,4,8-trioxa-benzocyclododecen-7-one

(2R,3R,4aR,7R,12aS)-octahydro-2,3-dimethoxy-2,3,7-trimethyl-4aH-[1,4]dioxino[2,3-c]oxecin-5(7H)-one

(2R,3R,4aR,7R,12aS)-octahydro-2,3-dimethoxy-2,3,7-trimethyl-4aH-[1,4]dioxino[2,3-c]oxecin-5(7H)-one

(E)-(2R,3R,4aS,9R,14aS)-2,3-Dimethoxy-2,3,9-trimethyl-2,3,4a,9,10,11,12,13,14,14a-decahydro-1,4,8-trioxa-benzocyclododecen-7-one

(E)-(2R,3R,4aS,9R,14aS)-2,3-Dimethoxy-2,3,9-trimethyl-2,3,4a,9,10,11,12,13,14,14a-decahydro-1,4,8-trioxa-benzocyclododecen-7-one

(E)-3-[(2S,3S,5R,6R)-3-((R)-6-Hydroxy-heptyl)-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl]-acrylic acid

(E)-3-[(2S,3S,5R,6R)-3-((R)-6-Hydroxy-heptyl)-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl]-acrylic acid

(E)-(2R,3R,4aS,9R,14aS)-2,3-Dimethoxy-2,3,9-trimethyl-2,3,4a,9,10,11,12,13,14,14a-decahydro-1,4,8-trioxa-benzocyclododecen-7-one

(E)-(2R,3R,4aS,9R,14aS)-2,3-Dimethoxy-2,3,9-trimethyl-2,3,4a,9,10,11,12,13,14,14a-decahydro-1,4,8-trioxa-benzocyclododecen-7-one

上游原料

(E)-3-[(2S,3S,5R,6R)-3-((R)-6-Hydroxy-heptyl)-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl]-acrylic acid methyl (E)-3-{(2S,3S,5R,6R)-3-[(R)-6-hydroxyheptyl]-5,6-dimethoxy-5,6-dimethyl-1,4-dioxan-2-yl}acrylate (2R,3R,4aR,7R,12aS)-octahydro-2,3-dimethoxy-2,3,7-trimethyl-4aH-[1,4]dioxino[2,3-c]oxecin-5(7H)-one

下游产品

(5S,6S,12R,Z)-5,6-dihydroxy-12-methyloxacyclododec-3-en-2-one (5S,6S,12R,E)-5,6-dihydroxy-12-methyloxacyclododec-3-en-2-one