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(4S,5R,10S,11R,15R)-(2E,8E)-15-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid

(4S,5R,10S,11R,15R)-(2E,8E)-15-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid

CAS号：851636-50-5

英文名：(4S,5R,10S,11R,15R)-(2E,8E)-15-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid

分子式：C24H40O13

分子量：536.567

合成路线

(4S,5R)-(E)-5-(t-butyl(dimethyl)silyloxy)-4-(β-methoxyethoxy)methoxy-2-hexenoic acid

(4S,5R)-(E)-5-(t-butyl(dimethyl)silyloxy)-4-(β-methoxyethoxy)methoxy-2-hexenoic acid

(4S,5R,10S,11R,15R)-(2E,8E)-15-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid

(4S,5R,10S,11R,15R)-(2E,8E)-15-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid

(4S,5R,10S,11R)-(2E,8E)-11-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5-methyl-6-oxa-1,7-dioxo-2,8-dodecadienoic acid tert-butyl ester

(4S,5R,10S,11R)-(2E,8E)-11-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5-methyl-6-oxa-1,7-dioxo-2,8-dodecadienoic acid tert-butyl ester

(4S,5R,10S,11R,15R)-(2E,8E)-15-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid

(4S,5R,10S,11R,15R)-(2E,8E)-15-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid

(4S,5R,10S,11R,15R)-(2E,8E)-15-(tert-butyl(dimethyl)silyloxy)-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid tert-butyl ester

(4S,5R,10S,11R,15R)-(2E,8E)-15-(tert-butyl(dimethyl)silyloxy)-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid tert-butyl ester

(4S,5R,10S,11R,15R)-(2E,8E)-15-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid

(4S,5R,10S,11R,15R)-(2E,8E)-15-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid

(4S,5R)-(E)-5-hydroxy-4-(β-methoxyethoxy)methoxy-2-hexenoic acid tert-butyl ester

(4S,5R)-(E)-5-hydroxy-4-(β-methoxyethoxy)methoxy-2-hexenoic acid tert-butyl ester

(4S,5R,10S,11R,15R)-(2E,8E)-15-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid

(4S,5R,10S,11R,15R)-(2E,8E)-15-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid

(4S,5R,10S,11R)-(2E,8E)-11-(tert-butyl(dimethyl)silyloxy)-4,10-bis[(2-methoxyethoxy)methoxy]-5-methyl-6-oxa-1,7-dioxo-2,8-dodecadienoic acid tert-butyl ester

(4S,5R,10S,11R)-(2E,8E)-11-(tert-butyl(dimethyl)silyloxy)-4,10-bis[(2-methoxyethoxy)methoxy]-5-methyl-6-oxa-1,7-dioxo-2,8-dodecadienoic acid tert-butyl ester

(4S,5R,10S,11R,15R)-(2E,8E)-15-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid

(4S,5R,10S,11R,15R)-(2E,8E)-15-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid

上游原料

(4S,5R,10S,11R)-(2E,8E)-11-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5-methyl-6-oxa-1,7-dioxo-2,8-dodecadienoic acid tert-butyl ester (4S,5R)-(E)-5-(t-butyl(dimethyl)silyloxy)-4-(β-methoxyethoxy)methoxy-2-hexenoic acid (4S,5R,10S,11R,15R)-(2E,8E)-15-(tert-butyl(dimethyl)silyloxy)-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid tert-butyl ester (4S,5R,10S,11R)-(2E,8E)-11-(tert-butyl(dimethyl)silyloxy)-4,10-bis[(2-methoxyethoxy)methoxy]-5-methyl-6-oxa-1,7-dioxo-2,8-dodecadienoic acid tert-butyl ester (4S,5R)-(E)-5-hydroxy-4-(β-methoxyethoxy)methoxy-2-hexenoic acid tert-butyl ester

下游产品

(5S,6R,11S,12R,16R)-(3E,9E)-5,11-bis[(2-methoxyethoxy)methyl]-6,12,16-trimethyl-1,7,13-trioxacyclohexadeca-3,9-diene-2,8,14-trione