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(E)-(2R,3S,4S,6R,7R,10S)-2,7-Bis-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-4,6,8,10-tetramethyl-5,11-dioxo-dodec-8-enoic acid allyl ester

(E)-(2R,3S,4S,6R,7R,10S)-2,7-Bis-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-4,6,8,10-tetramethyl-5,11-dioxo-dodec-8-enoic acid allyl ester

CAS号：852952-71-7

英文名：(E)-(2R,3S,4S,6R,7R,10S)-2,7-Bis-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-4,6,8,10-tetramethyl-5,11-dioxo-dodec-8-enoic acid allyl ester

分子式：C32H60O7Si2

分子量：612.986

合成路线

(2R,3S,4S,5R)-5-[(3,4-dimethoxybenzyl)oxy]-3-methoxy-4-methyl-2-[(tert-butyldimethylsilyl)oxy]heptanal

(2R,3S,4S,5R)-5-[(3,4-dimethoxybenzyl)oxy]-3-methoxy-4-methyl-2-[(tert-butyldimethylsilyl)oxy]heptanal

(E)-(2R,3S,4S,6R,7R,10S)-2,7-Bis-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-4,6,8,10-tetramethyl-5,11-dioxo-dodec-8-enoic acid allyl ester

(E)-(2R,3S,4S,6R,7R,10S)-2,7-Bis-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-4,6,8,10-tetramethyl-5,11-dioxo-dodec-8-enoic acid allyl ester

(2R,3S,4S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-4-methyl-5-oxo-heptanoic acid allyl ester

(2R,3S,4S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-4-methyl-5-oxo-heptanoic acid allyl ester

(E)-(2R,3S,4S,6R,7R,10S)-2,7-Bis-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-4,6,8,10-tetramethyl-5,11-dioxo-dodec-8-enoic acid allyl ester

(E)-(2R,3S,4S,6R,7R,10S)-2,7-Bis-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-4,6,8,10-tetramethyl-5,11-dioxo-dodec-8-enoic acid allyl ester

(E)-(2R,3S,4S,6R,7R,10S,11R)-2-(tert-Butyl-dimethyl-silanyloxy)-11-(3,4-dimethoxy-benzyloxy)-7-hydroxy-3-methoxy-4,6,8,10-tetramethyl-5-oxo-dodec-8-enoic acid allyl ester

(E)-(2R,3S,4S,6R,7R,10S,11R)-2-(tert-Butyl-dimethyl-silanyloxy)-11-(3,4-dimethoxy-benzyloxy)-7-hydroxy-3-methoxy-4,6,8,10-tetramethyl-5-oxo-dodec-8-enoic acid allyl ester

(E)-(2R,3S,4S,6R,7R,10S)-2,7-Bis-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-4,6,8,10-tetramethyl-5,11-dioxo-dodec-8-enoic acid allyl ester

(E)-(2R,3S,4S,6R,7R,10S)-2,7-Bis-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-4,6,8,10-tetramethyl-5,11-dioxo-dodec-8-enoic acid allyl ester

上游原料

(E)-(2R,3S,4S,6R,7R,10S,11R)-2-(tert-Butyl-dimethyl-silanyloxy)-11-(3,4-dimethoxy-benzyloxy)-7-hydroxy-3-methoxy-4,6,8,10-tetramethyl-5-oxo-dodec-8-enoic acid allyl ester (2R,3S,4S,5R)-5-[(3,4-dimethoxybenzyl)oxy]-3-methoxy-4-methyl-2-[(tert-butyldimethylsilyl)oxy]heptanal (2R,3S,4S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-4-methyl-5-oxo-heptanoic acid allyl ester

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