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(Z)-(4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-hydroxymethylene-6-(triethylsilyloxy)decahydronaphthalen-1-one

(Z)-(4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-hydroxymethylene-6-(triethylsilyloxy)decahydronaphthalen-1-one

CAS号：854520-42-6

英文名：(Z)-(4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-hydroxymethylene-6-(triethylsilyloxy)decahydronaphthalen-1-one

分子式：C28H54O4Si2

分子量：510.897

合成路线

(4aS,5S,6R,8aS)-5,8a-dimethyl-6-hydroxy-5-(3-hydroxypropyl)decahydronaphthalen-1-one 1-ethylene acetal

(4aS,5S,6R,8aS)-5,8a-dimethyl-6-hydroxy-5-(3-hydroxypropyl)decahydronaphthalen-1-one 1-ethylene acetal

(Z)-(4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-hydroxymethylene-6-(triethylsilyloxy)decahydronaphthalen-1-one

(Z)-(4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-hydroxymethylene-6-(triethylsilyloxy)decahydronaphthalen-1-one

(4aS,5S,6R,8aS)-5,8a-dimethyl-6-hydroxy-5-(3-hydroxypropyl)decahydronaphthalen-1-one

(4aS,5S,6R,8aS)-5,8a-dimethyl-6-hydroxy-5-(3-hydroxypropyl)decahydronaphthalen-1-one

(Z)-(4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-hydroxymethylene-6-(triethylsilyloxy)decahydronaphthalen-1-one

(Z)-(4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-hydroxymethylene-6-(triethylsilyloxy)decahydronaphthalen-1-one

(4aS,5S,6R,8aS)-5-allyl-5,8a-dimethyl-6-(hydroxy)decahydronaphthalen-1-one 1-ethylene acetal

(4aS,5S,6R,8aS)-5-allyl-5,8a-dimethyl-6-(hydroxy)decahydronaphthalen-1-one 1-ethylene acetal

(Z)-(4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-hydroxymethylene-6-(triethylsilyloxy)decahydronaphthalen-1-one

(Z)-(4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-hydroxymethylene-6-(triethylsilyloxy)decahydronaphthalen-1-one

(4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-6-(hydroxy)decahydronaphthalen-1-one

(4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-6-(hydroxy)decahydronaphthalen-1-one

(Z)-(4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-hydroxymethylene-6-(triethylsilyloxy)decahydronaphthalen-1-one

(Z)-(4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-hydroxymethylene-6-(triethylsilyloxy)decahydronaphthalen-1-one

(4aS)-1,4aβ-dimethyl-4,4a,7,8-tetrahydronaphthalene-2,5(3H,6H)-dione-5-ethyeneacetal

(4aS)-1,4aβ-dimethyl-4,4a,7,8-tetrahydronaphthalene-2,5(3H,6H)-dione-5-ethyeneacetal

(Z)-(4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-hydroxymethylene-6-(triethylsilyloxy)decahydronaphthalen-1-one

(Z)-(4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-hydroxymethylene-6-(triethylsilyloxy)decahydronaphthalen-1-one

上游原料

(4aS)-1,4aβ-dimethyl-4,4a,7,8-tetrahydronaphthalene-2,5(3H,6H)-dione-5-ethyeneacetal (4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-6-(hydroxy)decahydronaphthalen-1-one (4aS,5S,6R,8aS)-5,8a-dimethyl-6-hydroxy-5-(3-hydroxypropyl)decahydronaphthalen-1-one (4aS,5S,6R,8aS)-5,8a-dimethyl-6-hydroxy-5-(3-hydroxypropyl)decahydronaphthalen-1-one 1-ethylene acetal (4aS,5S,6R,8aS)-5-allyl-5,8a-dimethyl-6-(hydroxy)decahydronaphthalen-1-one 1-ethylene acetal

下游产品

(4aR,5S,6R,8aR)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-6-(triethylsilyloxy)-3,4,4a,5,6,7,8,8a-octahydronaphthalene-2-carbaldehyde (Z)-(1R,4aS,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-(1-ethoxyethyl)oxymethylene-6-(triethylsilyloxy)decahydronaphthalen-1-ol