百科

3-[(1R,4aR,5S,6R,8aR)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalen-1-yl]methyl-2-methoxy-5,6-dimethyl-4H-pyran-4-one

3-[(1R,4aR,5S,6R,8aR)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalen-1-yl]methyl-2-methoxy-5,6-dimethyl-4H-pyran-4-one

CAS号：854520-51-7

英文名：3-[(1R,4aR,5S,6R,8aR)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalen-1-yl]methyl-2-methoxy-5,6-dimethyl-4H-pyran-4-one

分子式：C37H66O5Si2

分子量：647.088

合成路线

3-bromo-2-methoxy-5,6-dimethyl-4H-pyran-4-one

3-bromo-2-methoxy-5,6-dimethyl-4H-pyran-4-one

3-[(1R,4aR,5S,6R,8aR)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalen-1-yl]methyl-2-methoxy-5,6-dimethyl-4H-pyran-4-one

3-[(1R,4aR,5S,6R,8aR)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalen-1-yl]methyl-2-methoxy-5,6-dimethyl-4H-pyran-4-one

(1R,4aR,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalene-1-carbaldehyde

(1R,4aR,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalene-1-carbaldehyde

3-[(1R,4aR,5S,6R,8aR)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalen-1-yl]methyl-2-methoxy-5,6-dimethyl-4H-pyran-4-one

3-[(1R,4aR,5S,6R,8aR)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalen-1-yl]methyl-2-methoxy-5,6-dimethyl-4H-pyran-4-one

(1R,4aR,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalene-1-methanol

(1R,4aR,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalene-1-methanol

3-[(1R,4aR,5S,6R,8aR)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalen-1-yl]methyl-2-methoxy-5,6-dimethyl-4H-pyran-4-one

3-[(1R,4aR,5S,6R,8aR)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalen-1-yl]methyl-2-methoxy-5,6-dimethyl-4H-pyran-4-one

3-[[(1R,4aR,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalen-1-yl]hydroxymethyl]-2-methoxy-5,6-dimethyl-4H-pyran-4-one

3-[[(1R,4aR,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalen-1-yl]hydroxymethyl]-2-methoxy-5,6-dimethyl-4H-pyran-4-one

3-[(1R,4aR,5S,6R,8aR)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalen-1-yl]methyl-2-methoxy-5,6-dimethyl-4H-pyran-4-one

3-[(1R,4aR,5S,6R,8aR)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalen-1-yl]methyl-2-methoxy-5,6-dimethyl-4H-pyran-4-one

上游原料

3-[[(1R,4aR,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalen-1-yl]hydroxymethyl]-2-methoxy-5,6-dimethyl-4H-pyran-4-one (1R,4aR,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalene-1-methanol 3-bromo-2-methoxy-5,6-dimethyl-4H-pyran-4-one (1R,4aR,5S,6R,8aS)-5-(3-tert-butyldimethylsilyloxypropyl)-5,8a-dimethyl-2-methylene-6-(triethylsilyloxy)decahydronaphthalene-1-carbaldehyde

下游产品

3-[(1R,4aR,5S,6R,8aR)-5,8a-dimethyl-2-methylene-5-(3-oxopropyl)-6-(triethylsilyloxy)decahydronaphthalen-1-yl]-methyl-2-methoxy-5,6-dimethyl-4H-pyran-4-one 3-[[(4aR,6aR,7R,10aR,10bR)-3-hydroxy-6a,10b-dimethyl-8-(methylene)dodecahydro-1H-benzo[f]chromen-7-yl]-methyl]-2-methoxy-5,6-dimethyl-4H-pyran-4-one