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(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enal

(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enal

CAS号：854749-23-8

英文名：(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enal

分子式：C31H40O6

分子量：508.646

合成路线

(5S,7R,8R)-8-Benzyloxymethoxy-5-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-nonanal

(5S,7R,8R)-8-Benzyloxymethoxy-5-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-nonanal

(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enal

(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enal

(8S,10R,11R)-11-Benzyloxymethoxy-8-(tert-butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,3-dimethyl-dodec-1-en-4-ol

(8S,10R,11R)-11-Benzyloxymethoxy-8-(tert-butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,3-dimethyl-dodec-1-en-4-ol

(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enal

(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enal

(E)-(9S,11R,12R)-12-Benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-11-(4-methoxy-benzyloxy)-4,4-dimethyl-5-oxo-tridec-2-enethioic acid S-ethyl ester

(E)-(9S,11R,12R)-12-Benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-11-(4-methoxy-benzyloxy)-4,4-dimethyl-5-oxo-tridec-2-enethioic acid S-ethyl ester

(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enal

(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enal

(7S,9R,10R)-10-Benzyloxymethoxy-7-(tert-butyl-dimethyl-silanyloxy)-9-(4-methoxy-benzyloxy)-2,2-dimethyl-3-oxo-undecanal

(7S,9R,10R)-10-Benzyloxymethoxy-7-(tert-butyl-dimethyl-silanyloxy)-9-(4-methoxy-benzyloxy)-2,2-dimethyl-3-oxo-undecanal

(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enal

(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enal

(8S,10R,11R)-11-Benzyloxymethoxy-8-(tert-butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,3-dimethyl-dodec-1-en-4-one

(8S,10R,11R)-11-Benzyloxymethoxy-8-(tert-butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,3-dimethyl-dodec-1-en-4-one

(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enal

(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enal

上游原料

(E)-(9S,11R,12R)-12-Benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-11-(4-methoxy-benzyloxy)-4,4-dimethyl-5-oxo-tridec-2-enethioic acid S-ethyl ester (7S,9R,10R)-10-Benzyloxymethoxy-7-(tert-butyl-dimethyl-silanyloxy)-9-(4-methoxy-benzyloxy)-2,2-dimethyl-3-oxo-undecanal (5S,7R,8R)-8-Benzyloxymethoxy-5-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-nonanal (8S,10R,11R)-11-Benzyloxymethoxy-8-(tert-butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,3-dimethyl-dodec-1-en-4-one (8S,10R,11R)-11-Benzyloxymethoxy-8-(tert-butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,3-dimethyl-dodec-1-en-4-ol

下游产品

{2-[(2S,6R)-6-((E)-3-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-3-methyl-but-1-enyl)-4-methylene-tetrahydro-pyran-2-yl]-ethoxy}-tert-butyl-diphenyl-silane