百科

(1R,5S,6S,7S,8S)-8-benzyloxy-6,7-isopropylidenedioxy-2-oxabicyclo[3.3.0]oct-3-ol

(1R,5S,6S,7S,8S)-8-benzyloxy-6,7-isopropylidenedioxy-2-oxabicyclo[3.3.0]oct-3-ol

CAS号：855517-39-4

英文名：(1R,5S,6S,7S,8S)-8-benzyloxy-6,7-isopropylidenedioxy-2-oxabicyclo[3.3.0]oct-3-ol

分子式：C17H22O5

分子量：306.354

合成路线

(1R,5R,6S,7S,8S)-8-benzyloxy-6,7-isopropylidenedioxy-2-oxabicyclo[3.3.0]oct-3-one

(1R,5R,6S,7S,8S)-8-benzyloxy-6,7-isopropylidenedioxy-2-oxabicyclo[3.3.0]oct-3-one

(1R,5S,6S,7S,8S)-8-benzyloxy-6,7-isopropylidenedioxy-2-oxabicyclo[3.3.0]oct-3-ol

(1R,5S,6S,7S,8S)-8-benzyloxy-6,7-isopropylidenedioxy-2-oxabicyclo[3.3.0]oct-3-ol

(1R,5R,8R)-8-benzyloxy-2-oxabicyclo[3.3.0]oct-6-en-3-one

(1R,5R,8R)-8-benzyloxy-2-oxabicyclo[3.3.0]oct-6-en-3-one

(1R,5S,6S,7S,8S)-8-benzyloxy-6,7-isopropylidenedioxy-2-oxabicyclo[3.3.0]oct-3-ol

(1R,5S,6S,7S,8S)-8-benzyloxy-6,7-isopropylidenedioxy-2-oxabicyclo[3.3.0]oct-3-ol

(1R,5R,8R)-8-Hydroxy-2-oxabicyclo[3.3.0]oct-6-en-3-one

(1R,5R,8R)-8-Hydroxy-2-oxabicyclo[3.3.0]oct-6-en-3-one

(1R,5S,6S,7S,8S)-8-benzyloxy-6,7-isopropylidenedioxy-2-oxabicyclo[3.3.0]oct-3-ol

(1R,5S,6S,7S,8S)-8-benzyloxy-6,7-isopropylidenedioxy-2-oxabicyclo[3.3.0]oct-3-ol

上游原料

(1R,5R,8R)-8-benzyloxy-2-oxabicyclo[3.3.0]oct-6-en-3-one (1R,5R,6S,7S,8S)-8-benzyloxy-6,7-isopropylidenedioxy-2-oxabicyclo[3.3.0]oct-3-one (1R,5R,8R)-8-Hydroxy-2-oxabicyclo[3.3.0]oct-6-en-3-one

下游产品

(1R,2R,3S,4S,5R)-1-O-mesyl-2-O-(benzylcarbamoyl)-3,4-O-isopropylidene-5-acetoxymethyl-cyclopentane-1,2,3,4-tetrol (1R,2S,3S,4S,5S)-2-O-benzyl-3,4-O-isopropylidene-5-iodomethyl-cyclopentane-1,2,3,4-tetrol (1R,2S,3S,4S,5R)-1-formyloxy-2-benzyloxy-3,4-O-isopropylidene-5-iodomethyl-1,2,3,4-cyclopentane-tetrol (1R,2R,3R,4S,5R)-1-O-mesyl-3,4-O-isopropylidene-5-acetoxymethyl-cyclopentane-1,2,3,4-tetrol (1R,2S,3S,4S,5S)-2-O-benzyl-3,4-O-isopropylidene-5-acetoxymethyl-1,2,3,4-cyclopentane-tetrol (1S,2S,3S,4S,5S)-4-N-benzyl-5-acetoxymethyl-7,8-isopropylidenedioxy-2-oxa-4-azabicyclo[3.3.0]oct-3-one (1S,2S,3S,4S,5R)-4-N-benzylamino-5-hydroxymethyl-cyclopentane-1,2,3-triol (1R,2R,3S,4S,5R)-1-O-mesyl-2-O-benzyl-3,4-O-isopropylidene-5-acetoxymethyl-cyclopentane-1,2,3,4-tetrol (1S,2S,3S,4S,5R)-4-benzylamino-5-(hydroxymethyl)-1,2-isopropylidenecyclopentane-1,2,3-triol