百科

(4R,5S)-3-[(2'R,3'S,6'R)-7'-tert-butyldimethylsilyloxy-3'-hydroxy-2',5'-dimethyl-1'-heptanoyl]-4-methyl-5-phenyl-2-oxazolidinone

(4R,5S)-3-[(2'R,3'S,6'R)-7'-tert-butyldimethylsilyloxy-3'-hydroxy-2',5'-dimethyl-1'-heptanoyl]-4-methyl-5-phenyl-2-oxazolidinone

CAS号：856190-87-9

英文名：(4R,5S)-3-[(2'R,3'S,6'R)-7'-tert-butyldimethylsilyloxy-3'-hydroxy-2',5'-dimethyl-1'-heptanoyl]-4-methyl-5-phenyl-2-oxazolidinone

分子式：C25H41NO5Si

分子量：463.682

合成路线

(2S)-(+)-(tert-butyl-dimethyl)-(3-iodo-2-methyl-propoxy)-silane

(2S)-(+)-(tert-butyl-dimethyl)-(3-iodo-2-methyl-propoxy)-silane

(4R,5S)-3-[(2'R,3'S,6'R)-7'-tert-butyldimethylsilyloxy-3'-hydroxy-2',5'-dimethyl-1'-heptanoyl]-4-methyl-5-phenyl-2-oxazolidinone

(4R,5S)-3-[(2'R,3'S,6'R)-7'-tert-butyldimethylsilyloxy-3'-hydroxy-2',5'-dimethyl-1'-heptanoyl]-4-methyl-5-phenyl-2-oxazolidinone

(5R)-6-(tert-butyldimethylsilyloxy)-5-methylhex-1-ene

(5R)-6-(tert-butyldimethylsilyloxy)-5-methylhex-1-ene

(4R,5S)-3-[(2'R,3'S,6'R)-7'-tert-butyldimethylsilyloxy-3'-hydroxy-2',5'-dimethyl-1'-heptanoyl]-4-methyl-5-phenyl-2-oxazolidinone

(4R,5S)-3-[(2'R,3'S,6'R)-7'-tert-butyldimethylsilyloxy-3'-hydroxy-2',5'-dimethyl-1'-heptanoyl]-4-methyl-5-phenyl-2-oxazolidinone

上游原料

(5R)-6-(tert-butyldimethylsilyloxy)-5-methylhex-1-ene (2S)-(+)-(tert-butyl-dimethyl)-(3-iodo-2-methyl-propoxy)-silane

下游产品

(2R,3S,6R)-3,7-di(tert-butyldimethylsilyloxy)-2,6-dimethylheptanal (3E,7E,2R,9R,10R,11S,14R)-1-benzenesulfonyl-9,11,15-tris(tert-butyldimethylsilyloxy)-2,10,14-trimethylpentadeca-3,7-diene (3S,4S,7R)-3,7-bis(tert-butyldimethylsilyloxy)-2,6-dimethylheptanethioic acid S-ethyl ester (8E,12E,2R,5S,6S,7R,14R)-1,5-bis(tert-butyldimethylsilyloxy)-15-(4-methoxybenzyloxy)-2,6,14-trimethylpentadeca-8,12-dien-7-ol (3E,7E,2R,9R,11S,14R)-9,11,15-tris(tert-butyldimethylsilyloxy)-1-(4-methoxybenzyloxy)-2,10,14-trimethylpentadeca-3,7-diene (3E,7E,2R,9R,10R,11S,14R)-9,11,15-tris(tert-butyldimethylsilyloxy)-2,10,14-trimethyl-1-phenylsulfanylpentadeca-3,7-diene