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(3S,4S,7R)-3,7-bis(tert-butyldimethylsilyloxy)-2,6-dimethylheptanethioic acid S-ethyl ester

(3S,4S,7R)-3,7-bis(tert-butyldimethylsilyloxy)-2,6-dimethylheptanethioic acid S-ethyl ester

CAS号：856190-88-0

英文名：(3S,4S,7R)-3,7-bis(tert-butyldimethylsilyloxy)-2,6-dimethylheptanethioic acid S-ethyl ester

分子式：C23H50O3SSi2

分子量：462.877

合成路线

(2S)-(+)-(tert-butyl-dimethyl)-(3-iodo-2-methyl-propoxy)-silane

(2S)-(+)-(tert-butyl-dimethyl)-(3-iodo-2-methyl-propoxy)-silane

(3S,4S,7R)-3,7-bis(tert-butyldimethylsilyloxy)-2,6-dimethylheptanethioic acid S-ethyl ester

(3S,4S,7R)-3,7-bis(tert-butyldimethylsilyloxy)-2,6-dimethylheptanethioic acid S-ethyl ester

(5R)-6-(tert-butyldimethylsilyloxy)-5-methylhex-1-ene

(5R)-6-(tert-butyldimethylsilyloxy)-5-methylhex-1-ene

(3S,4S,7R)-3,7-bis(tert-butyldimethylsilyloxy)-2,6-dimethylheptanethioic acid S-ethyl ester

(3S,4S,7R)-3,7-bis(tert-butyldimethylsilyloxy)-2,6-dimethylheptanethioic acid S-ethyl ester

(4R,5S)-3-[(2'R,3'S,6'R)-7'-tert-butyldimethylsilyloxy-3'-hydroxy-2',5'-dimethyl-1'-heptanoyl]-4-methyl-5-phenyl-2-oxazolidinone

(4R,5S)-3-[(2'R,3'S,6'R)-7'-tert-butyldimethylsilyloxy-3'-hydroxy-2',5'-dimethyl-1'-heptanoyl]-4-methyl-5-phenyl-2-oxazolidinone

(3S,4S,7R)-3,7-bis(tert-butyldimethylsilyloxy)-2,6-dimethylheptanethioic acid S-ethyl ester

(3S,4S,7R)-3,7-bis(tert-butyldimethylsilyloxy)-2,6-dimethylheptanethioic acid S-ethyl ester

上游原料

(5R)-6-(tert-butyldimethylsilyloxy)-5-methylhex-1-ene (2S)-(+)-(tert-butyl-dimethyl)-(3-iodo-2-methyl-propoxy)-silane (4R,5S)-3-[(2'R,3'S,6'R)-7'-tert-butyldimethylsilyloxy-3'-hydroxy-2',5'-dimethyl-1'-heptanoyl]-4-methyl-5-phenyl-2-oxazolidinone

下游产品

(2R,3S,6R)-3,7-di(tert-butyldimethylsilyloxy)-2,6-dimethylheptanal piperidine-2-carboxylic acid 11,13-bis-(tert-butyl-dimethyl-silanyloxy)-16-carboxy-1-[2-(2,3-dimethoxy-5-methoxymethoxy-2,3-dimethyl-octahydro-benzo[1,4]dioxin-6-yl)-1-methyl-ethyl]-4,12-dimethyl-heptadeca-5,9-dienyl ester (3E,7E,2R,9R,10R,11S,14R)-1-benzenesulfonyl-9,11,15-tris(tert-butyldimethylsilyloxy)-2,10,14-trimethylpentadeca-3,7-diene (7E,11E,2R,3S,6R,13S,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol (7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol (8E,12E,2R,5S,6S,7R,14R)-1,5-bis(tert-butyldimethylsilyloxy)-15-(4-methoxybenzyloxy)-2,6,14-trimethylpentadeca-8,12-dien-7-ol (3E,7E,2R,9R,11S,14R)-9,11,15-tris(tert-butyldimethylsilyloxy)-1-(4-methoxybenzyloxy)-2,10,14-trimethylpentadeca-3,7-diene (3E,7E,2R,9R,10R,11S,14R)-9,11,15-tris(tert-butyldimethylsilyloxy)-2,10,14-trimethyl-1-phenylsulfanylpentadeca-3,7-diene