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(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

CAS号：856191-07-6

英文名：(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

分子式：C61H114O12SSi3

分子量：1155.87

合成路线

(2S)-(+)-(tert-butyl-dimethyl)-(3-iodo-2-methyl-propoxy)-silane

(2S)-(+)-(tert-butyl-dimethyl)-(3-iodo-2-methyl-propoxy)-silane

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

4'-methoxybenzyl (3E,2R)-2-methyloct-3-en-7-ynyl ether

4'-methoxybenzyl (3E,2R)-2-methyloct-3-en-7-ynyl ether

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(4R,5S)-3-[(2'R,3'S,6'R)-3',7'-bis(tert-butyldimethylsilyloxy)-2',5'-dimethyl-1'-heptanoyl]-4-methyl-5-phenyl-2-oxazolidinone

(4R,5S)-3-[(2'R,3'S,6'R)-3',7'-bis(tert-butyldimethylsilyloxy)-2',5'-dimethyl-1'-heptanoyl]-4-methyl-5-phenyl-2-oxazolidinone

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(2E,4R)-1-bromo-5-(4-methoxybenzyloxy)-4-methyl-2-pentene

(2E,4R)-1-bromo-5-(4-methoxybenzyloxy)-4-methyl-2-pentene

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(2S,3S,5R,6R,1'S,2'R,2''R,3''R)-5-[2'-(3'',4''-bis(benzyloxy)-2''-methylbutyl)-1'-methoxymethoxybut-3'-enyl]-2,3-dimethoxy-2,3-dimethyl-6-vinyl[1,4]dioxane

(2S,3S,5R,6R,1'S,2'R,2''R,3''R)-5-[2'-(3'',4''-bis(benzyloxy)-2''-methylbutyl)-1'-methoxymethoxybut-3'-enyl]-2,3-dimethoxy-2,3-dimethyl-6-vinyl[1,4]dioxane

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(8E,12E,2R,5S,6S,7R,14R)-1,5-bis(tert-butyldimethylsilyloxy)-15-(4-methoxybenzyloxy)-2,6,14-trimethylpentadeca-8,12-dien-7-ol

(8E,12E,2R,5S,6S,7R,14R)-1,5-bis(tert-butyldimethylsilyloxy)-15-(4-methoxybenzyloxy)-2,6,14-trimethylpentadeca-8,12-dien-7-ol

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(3E,7E,2R,9R,10R,11S,14R)-9,11,15-tris(tert-butyldimethylsilyloxy)-2,10,14-trimethyl-1-phenylsulfanylpentadeca-3,7-diene

(3E,7E,2R,9R,10R,11S,14R)-9,11,15-tris(tert-butyldimethylsilyloxy)-2,10,14-trimethyl-1-phenylsulfanylpentadeca-3,7-diene

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(2R,3S,6R)-3,7-di(tert-butyldimethylsilyloxy)-2,6-dimethylheptanal

(2R,3S,6R)-3,7-di(tert-butyldimethylsilyloxy)-2,6-dimethylheptanal

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(3E,2R)-1-(4-methoxybenzyloxy)-2-methyl-8-(trimethylsilyloxy)-oct-3-en-7-yne

(3E,2R)-1-(4-methoxybenzyloxy)-2-methyl-8-(trimethylsilyloxy)-oct-3-en-7-yne

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(3S,4S,7R)-3,7-bis(tert-butyldimethylsilyloxy)-2,6-dimethylheptanethioic acid S-ethyl ester

(3S,4S,7R)-3,7-bis(tert-butyldimethylsilyloxy)-2,6-dimethylheptanethioic acid S-ethyl ester

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

(7E,11E,2R,3S,6R,13R,14R,15S,18R,2'S,3'S,4a'S,5'S,6'S,8a'R)-5-benzenesulfonyl-13,15,19-tris(tert-butyldimethylsilyloxy)-1-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-2,6,14,18,-tetramethylnonadeca-7,11-dien-3-ol

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上游原料

(2R,3S,6R)-3,7-di(tert-butyldimethylsilyloxy)-2,6-dimethylheptanal (2S,3S,5R,6R,1'S,2'R,2''R,3''R)-5-[2'-(3'',4''-bis(benzyloxy)-2''-methylbutyl)-1'-methoxymethoxybut-3'-enyl]-2,3-dimethoxy-2,3-dimethyl-6-vinyl[1,4]dioxane 4'-methoxybenzyl (3E,2R)-2-methyloct-3-en-7-ynyl ether (2R,3R,5S,6S,1'S,2'R,2''R,3''R)-{3-[2'-(3'',4''-bis(benzyloxy)-2''-methylbutyl)-1'-methoxymethoxybut-3'-enyl]-5,6-dimethoxy-5,6-dimethyl[1,4]dioxan-2-yl}methanol (3E,7E,2R,9R,10R,11S,14R)-1-benzenesulfonyl-9,11,15-tris(tert-butyldimethylsilyloxy)-2,10,14-trimethylpentadeca-3,7-diene (3S,4S,7R)-3,7-bis(tert-butyldimethylsilyloxy)-2,6-dimethylheptanethioic acid S-ethyl ester (2R,3R,2'S,3'S,4a'S,5'S,6'S,8a'R)-4-(2',3'-dimethoxy-5'-methoxymethoxy-2',3'-dimethyloctahydrobenzo[1',4']dioxin-6'-yl)-3-methylbutane-1,2-diol (2E,4R)-1-bromo-5-(4-methoxybenzyloxy)-4-methyl-2-pentene (2S)-(+)-(tert-butyl-dimethyl)-(3-iodo-2-methyl-propoxy)-silane (4R,5S)-3-[(2'R,3'S,6'R)-3',7'-bis(tert-butyldimethylsilyloxy)-2',5'-dimethyl-1'-heptanoyl]-4-methyl-5-phenyl-2-oxazolidinone (2S,3S,4aS,5S,6S,8aR,2'R)-2,3-dimethoxy-5-methoxymethoxy-2,3-dimethyl-6-[2'-((R)-oxiranyl)propyl]octahydrobenzo[1,4]dioxine (5R)-6-(tert-butyldimethylsilyloxy)-5-methylhex-1-ene (3E,2R)-1-(4-methoxybenzyloxy)-2-methyl-8-(trimethylsilyloxy)-oct-3-en-7-yne (8E,12E,2R,5S,6S,7R,14R)-1,5-bis(tert-butyldimethylsilyloxy)-15-(4-methoxybenzyloxy)-2,6,14-trimethylpentadeca-8,12-dien-7-ol (3E,7E,2R,9R,11S,14R)-9,11,15-tris(tert-butyldimethylsilyloxy)-1-(4-methoxybenzyloxy)-2,10,14-trimethylpentadeca-3,7-diene (2S,3S,4aR,5S,6R,8aR,2'R,3'R)-6-(3',4'-dibenzyloxy-2'-methylbutyl)-2,3-dimethoxy-5-methoxymethoxy-2,3-dimethyl-2,3,4a,5,6,8a-hexahydrobenzo[1,4]dioxine (3E,7E,2R,9R,10R,11S,14R)-9,11,15-tris(tert-butyldimethylsilyloxy)-2,10,14-trimethyl-1-phenylsulfanylpentadeca-3,7-diene

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