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(2E,5Z)-(1R)-7-(tert-butyldiphenylsilyl)oxy-1-{(4R,5S)-2,2-dimethyl-5-[2-(4-methoxybenzyloxy)ethyl]-[1,3]-dioxolan-4-yl}-5-methyl-hepta-2,5-dien-1-ol

CAS号：856410-37-2

英文名：(2E,5Z)-(1R)-7-(tert-butyldiphenylsilyl)oxy-1-{(4R,5S)-2,2-dimethyl-5-[2-(4-methoxybenzyloxy)ethyl]-[1,3]-dioxolan-4-yl}-5-methyl-hepta-2,5-dien-1-ol

分子式：C39H52O6Si

分子量：644.912

合成路线

856410-50-9

(2E,5Z)-7-(tert-butyldiphenylsilyl)oxy-1-{(4R,5S)-2,2-dimethyl-5-[2-(4-methoxybenzyloxy)ethyl]-[1,3]-dioxolan-4-yl}-5-methyl-hepta-2,5-dien-1-one

856410-37-2

(2E,5Z)-(1R)-7-(tert-butyldiphenylsilyl)oxy-1-{(4R,5S)-2,2-dimethyl-5-[2-(4-methoxybenzyloxy)ethyl]-[1,3]-dioxolan-4-yl}-5-methyl-hepta-2,5-dien-1-ol

848691-97-4

(4R,5S)-ethyl 5-(2-((4-methoxybenzyl)oxy)ethyl)-2,2-dimethyl-1,3-dioxolane-4-carboxylate

856410-37-2

(2E,5Z)-(1R)-7-(tert-butyldiphenylsilyl)oxy-1-{(4R,5S)-2,2-dimethyl-5-[2-(4-methoxybenzyloxy)ethyl]-[1,3]-dioxolan-4-yl}-5-methyl-hepta-2,5-dien-1-ol

848691-96-3

ethyl (2R,3S)-2,3-dihydroxy-5-(4-methoxybenzyl)oxypentanoate

856410-37-2

(2E,5Z)-(1R)-7-(tert-butyldiphenylsilyl)oxy-1-{(4R,5S)-2,2-dimethyl-5-[2-(4-methoxybenzyloxy)ethyl]-[1,3]-dioxolan-4-yl}-5-methyl-hepta-2,5-dien-1-ol

848691-91-8

(Z)-5-(tert-butyldiphenylsilyl)oxy-3-methyl-1-trimethylsilyl-3-penten-1-yne

856410-37-2

(2E,5Z)-(1R)-7-(tert-butyldiphenylsilyl)oxy-1-{(4R,5S)-2,2-dimethyl-5-[2-(4-methoxybenzyloxy)ethyl]-[1,3]-dioxolan-4-yl}-5-methyl-hepta-2,5-dien-1-ol

172427-68-8

ethyl <2E>-5-(4-methoxybenzyloxy)-2-pentenoate

856410-37-2

(2E,5Z)-(1R)-7-(tert-butyldiphenylsilyl)oxy-1-{(4R,5S)-2,2-dimethyl-5-[2-(4-methoxybenzyloxy)ethyl]-[1,3]-dioxolan-4-yl}-5-methyl-hepta-2,5-dien-1-ol

223458-11-5

(3Z)-5-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)-3-methylpent-3-enol

856410-37-2

(2E,5Z)-(1R)-7-(tert-butyldiphenylsilyl)oxy-1-{(4R,5S)-2,2-dimethyl-5-[2-(4-methoxybenzyloxy)ethyl]-[1,3]-dioxolan-4-yl}-5-methyl-hepta-2,5-dien-1-ol

848691-95-2

methyl (Z)-5-(tert-butyldimethylsilyl)oxy-3-methyl-3-pentenoate

856410-37-2

(2E,5Z)-(1R)-7-(tert-butyldiphenylsilyl)oxy-1-{(4R,5S)-2,2-dimethyl-5-[2-(4-methoxybenzyloxy)ethyl]-[1,3]-dioxolan-4-yl}-5-methyl-hepta-2,5-dien-1-ol

848691-94-1

(Z)-5-(tert-butyldimethylsilyl)oxy-3-methyl-3-pentenoic acid

856410-37-2

(2E,5Z)-(1R)-7-(tert-butyldiphenylsilyl)oxy-1-{(4R,5S)-2,2-dimethyl-5-[2-(4-methoxybenzyloxy)ethyl]-[1,3]-dioxolan-4-yl}-5-methyl-hepta-2,5-dien-1-ol

上游原料

ethyl <2E>-5-(4-methoxybenzyloxy)-2-pentenoate ethyl (2R,3S)-2,3-dihydroxy-5-(4-methoxybenzyl)oxypentanoate (Z)-5-(tert-butyldiphenylsilyl)oxy-3-methyl-1-trimethylsilyl-3-penten-1-yne methyl (Z)-5-(tert-butyldimethylsilyl)oxy-3-methyl-3-pentenoate (Z)-5-(tert-butyldimethylsilyl)oxy-3-methyl-3-pentenoic acid (3Z)-5-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)-3-methylpent-3-enol (2E,5Z)-7-(tert-butyldiphenylsilyl)oxy-1-{(4R,5S)-2,2-dimethyl-5-[2-(4-methoxybenzyloxy)ethyl]-[1,3]-dioxolan-4-yl}-5-methyl-hepta-2,5-dien-1-one (4R,5S)-ethyl 5-(2-((4-methoxybenzyl)oxy)ethyl)-2,2-dimethyl-1,3-dioxolane-4-carboxylate

下游产品

(S)-2-((E)-2-{(4S,5S)-5-[2-(4-Methoxy-benzyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-vinyl)-4-methyl-3,6-dihydro-2H-pyran