百科

rac-methyl (4R,6aR,8aS,9S,12aR,12bR)-4-hydroxy-5,9,12a-trimethyl-4,5,6,6a,7,8,8a,9,10,11,12,12a-dodecahydro-4,12b-methanonaphtho[1,2-d]oxocine-9-carboxylate

CAS号：85706-54-3

英文名：rac-methyl (4R,6aR,8aS,9S,12aR,12bR)-4-hydroxy-5,9,12a-trimethyl-4,5,6,6a,7,8,8a,9,10,11,12,12a-dodecahydro-4,12b-methanonaphtho[1,2-d]oxocine-9-carboxylate

分子式：C21H32O4

分子量：348.476

合成路线

24402-17-3

4β-Methoxycarbonyl-4α,10β-dimethyl-1,2,3,4,5α,6,7,8β,10,12,13,14-dodecahydro-phenanthron-(12)

85706-54-3

rac-methyl (4R,6aR,8aS,9S,12aR,12bR)-4-hydroxy-5,9,12a-trimethyl-4,5,6,6a,7,8,8a,9,10,11,12,12a-dodecahydro-4,12b-methanonaphtho[1,2-d]oxocine-9-carboxylate

74501-03-4

85706-54-3

rac-methyl (4R,6aR,8aS,9S,12aR,12bR)-4-hydroxy-5,9,12a-trimethyl-4,5,6,6a,7,8,8a,9,10,11,12,12a-dodecahydro-4,12b-methanonaphtho[1,2-d]oxocine-9-carboxylate

74501-00-1

(3aS,5aR,6R,9aS,9bR,11aS)-2,6,9a-Trimethyl-11-methylene-1-oxo-tetradecahydro-cyclobuta[d]phenanthrene-6-carboxylic acid methyl ester

85706-54-3

rac-methyl (4R,6aR,8aS,9S,12aR,12bR)-4-hydroxy-5,9,12a-trimethyl-4,5,6,6a,7,8,8a,9,10,11,12,12a-dodecahydro-4,12b-methanonaphtho[1,2-d]oxocine-9-carboxylate

74500-99-5

(3aS,5aR,6R,9aS,9bR,11aS)-6,9a-Dimethyl-11-methylene-1-oxo-tetradecahydro-cyclobuta[d]phenanthrene-6-carboxylic acid methyl ester

85706-54-3

rac-methyl (4R,6aR,8aS,9S,12aR,12bR)-4-hydroxy-5,9,12a-trimethyl-4,5,6,6a,7,8,8a,9,10,11,12,12a-dodecahydro-4,12b-methanonaphtho[1,2-d]oxocine-9-carboxylate

74501-01-2

rac-methyl (3aR,5aS,6S,9aR,9bS,11aR)-2,6,9a-trimethyl-11-methylenedodecahydro-2H,10H-spiro[cyclobuta[d]phenanthrene-1,2'-[1,3]dioxolane]-6-carboxylate

85706-54-3

rac-methyl (4R,6aR,8aS,9S,12aR,12bR)-4-hydroxy-5,9,12a-trimethyl-4,5,6,6a,7,8,8a,9,10,11,12,12a-dodecahydro-4,12b-methanonaphtho[1,2-d]oxocine-9-carboxylate

74501-02-3

rac-methyl (3aR,5aS,6S,9aR,9bS,11aS)-2,6,9a-trimethyl-11-oxododecahydro-2H,10H-spiro[cyclobuta[d]phenanthrene-1,2'-[1,3]dioxolane]-6-carboxylate

85706-54-3

rac-methyl (4R,6aR,8aS,9S,12aR,12bR)-4-hydroxy-5,9,12a-trimethyl-4,5,6,6a,7,8,8a,9,10,11,12,12a-dodecahydro-4,12b-methanonaphtho[1,2-d]oxocine-9-carboxylate

上游原料

(3aS,5aR,6R,9aS,9bR,11aS)-6,9a-Dimethyl-11-methylene-1-oxo-tetradecahydro-cyclobuta[d]phenanthrene-6-carboxylic acid methyl ester rac-methyl (3aR,5aS,6S,9aR,9bS,11aS)-2,6,9a-trimethyl-11-oxododecahydro-2H,10H-spiro[cyclobuta[d]phenanthrene-1,2'-[1,3]dioxolane]-6-carboxylate (3aS,5aR,6R,9aS,9bR,11aS)-2,6,9a-Trimethyl-11-methylene-1-oxo-tetradecahydro-cyclobuta[d]phenanthrene-6-carboxylic acid methyl ester 4β-Methoxycarbonyl-4α,10β-dimethyl-1,2,3,4,5α,6,7,8β,10,12,13,14-dodecahydro-phenanthron-(12) rac-methyl (3aR,5aS,6S,9aR,9bS,11aR)-2,6,9a-trimethyl-11-methylenedodecahydro-2H,10H-spiro[cyclobuta[d]phenanthrene-1,2'-[1,3]dioxolane]-6-carboxylate

下游产品

aphidicolan-16β-ol