百科

{(2R,3S,4aR,6R,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-8a-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl}-acetonitrile

{(2R,3S,4aR,6R,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-8a-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl}-acetonitrile

CAS号：858346-46-0

英文名：{(2R,3S,4aR,6R,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-8a-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl}-acetonitrile

分子式：C43H69NO5Si3

分子量：764.268

合成路线

(2R,4aR,6S,7R,8aS)-6-Methyl-2-phenyl-6-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(2R,4aR,6S,7R,8aS)-6-Methyl-2-phenyl-6-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

{(2R,3S,4aR,6R,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-8a-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl}-acetonitrile

{(2R,3S,4aR,6R,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-8a-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl}-acetonitrile

2,2-Dimethyl-propionic acid (2R,3S,4aR,6R,8S,8aR)-8-acetoxy-6-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-2-(2,2-dimethyl-propionyloxymethyl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-3-yl ester

2,2-Dimethyl-propionic acid (2R,3S,4aR,6R,8S,8aR)-8-acetoxy-6-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-2-(2,2-dimethyl-propionyloxymethyl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-3-yl ester

{(2R,3S,4aR,6R,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-8a-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl}-acetonitrile

{(2R,3S,4aR,6R,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-8a-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl}-acetonitrile

上游原料

2,2-Dimethyl-propionic acid (2R,3S,4aR,6R,8S,8aR)-8-acetoxy-6-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-2-(2,2-dimethyl-propionyloxymethyl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-3-yl ester (2R,4aR,6S,7R,8aS)-6-Methyl-2-phenyl-6-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

下游产品

{(2R,3S,4aR,6R,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-8a-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl}-acetic acid {(2R,3S,4aR,6R,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-8a-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl}-acetaldehyde