百科

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

CAS号：858666-93-0

英文名：(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

分子式：C31H44O4Si

分子量：508.764

合成路线

(S)-5-Benzyloxy-4-hydroxy-pentanoic acid methoxy-methyl-amide

(S)-5-Benzyloxy-4-hydroxy-pentanoic acid methoxy-methyl-amide

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(2S,3S)-6-Benzyloxy-3-(4-methoxy-benzyloxy)-2-methyl-hexan-1-ol

(2S,3S)-6-Benzyloxy-3-(4-methoxy-benzyloxy)-2-methyl-hexan-1-ol

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(4R,5S)-3-((2R,3S)-6-Benzyloxy-3-hydroxy-2-methyl-hexanoyl)-4-methyl-5-phenyl-oxazolidin-2-one

(4R,5S)-3-((2R,3S)-6-Benzyloxy-3-hydroxy-2-methyl-hexanoyl)-4-methyl-5-phenyl-oxazolidin-2-one

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

tert-Butyl-[(2S,3S)-6-iodo-3-(4-methoxy-benzyloxy)-2-methyl-hexyloxy]-diphenyl-silane

tert-Butyl-[(2S,3S)-6-iodo-3-(4-methoxy-benzyloxy)-2-methyl-hexyloxy]-diphenyl-silane

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(4R,5S)-3-[(2R,3S)-6-Benzyloxy-3-(4-methoxy-benzyloxy)-2-methyl-hexanoyl]-4-methyl-5-phenyl-oxazolidin-2-one

(4R,5S)-3-[(2R,3S)-6-Benzyloxy-3-(4-methoxy-benzyloxy)-2-methyl-hexanoyl]-4-methyl-5-phenyl-oxazolidin-2-one

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(2S,9S,10S)-1-Benzyloxy-11-(tert-butyl-diphenyl-silanyloxy)-2,9-bis-(4-methoxy-benzyloxy)-10-methyl-undecan-5-one

(2S,9S,10S)-1-Benzyloxy-11-(tert-butyl-diphenyl-silanyloxy)-2,9-bis-(4-methoxy-benzyloxy)-10-methyl-undecan-5-one

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(S)-5-Benzyloxy-4-(4-methoxy-benzyloxy)-pentanoic acid methoxy-methyl-amide

(S)-5-Benzyloxy-4-(4-methoxy-benzyloxy)-pentanoic acid methoxy-methyl-amide

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(4S,5S)-6-(tert-Butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-5-methyl-hexan-1-ol

(4S,5S)-6-(tert-Butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-5-methyl-hexan-1-ol

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

5-((benzyloxy)methyl)dihydrofuran-2(3H)-one

5-((benzyloxy)methyl)dihydrofuran-2(3H)-one

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

(1'E,2S,5R,7S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(3'-hydroxy-1'-propenyl)-1,6-dioxaspiro[4.5]decane

上游原料

(4R,5S)-3-((2R,3S)-6-Benzyloxy-3-hydroxy-2-methyl-hexanoyl)-4-methyl-5-phenyl-oxazolidin-2-one tert-Butyl-[(2S,3S)-6-iodo-3-(4-methoxy-benzyloxy)-2-methyl-hexyloxy]-diphenyl-silane (S)-5-Benzyloxy-4-hydroxy-pentanoic acid methoxy-methyl-amide (S)-5-Benzyloxy-4-(4-methoxy-benzyloxy)-pentanoic acid methoxy-methyl-amide (4R,5S)-3-[(2R,3S)-6-Benzyloxy-3-(4-methoxy-benzyloxy)-2-methyl-hexanoyl]-4-methyl-5-phenyl-oxazolidin-2-one (2S,9S,10S)-1-Benzyloxy-11-(tert-butyl-diphenyl-silanyloxy)-2,9-bis-(4-methoxy-benzyloxy)-10-methyl-undecan-5-one (2S,3S)-6-Benzyloxy-3-(4-methoxy-benzyloxy)-2-methyl-hexan-1-ol (4S,5S)-6-(tert-Butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-5-methyl-hexan-1-ol 5-((benzyloxy)methyl)dihydrofuran-2(3H)-one

下游产品

(2S,5S,7S,1'S,2'S,1''S)-(+)-7-{2''-(tert-butyldiphenylsilyloxy)-1''-methylethyl}-2-(1',2'-epoxy-3'-iodo-2'-methylprop-1'-yl)-1,6-dioxaspiro[4.5]decane 3-((2S,3S)-3-{(2S,5S,7S)-7-[(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-1,6-dioxa-spiro[4.5]dec-2-yl}-2-methyl-oxiranyl)-2-hydroxy-propionic acid methyl ester