百科

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-trimethylsilanyloxy-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester

CAS号：860295-61-0

英文名：(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-trimethylsilanyloxy-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester

分子式：C29H54O6Si2

分子量：554.906

合成路线

860295-70-1

(2S,3R)-3-[(2R,6S)-6-((2S,3R)-2-Methoxy-3-methyl-4-oxo-pentyl)-5,6-dihydro-2H-pyran-2-ylmethyl]-oxirane-2-carbaldehyde

860295-61-0

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-trimethylsilanyloxy-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester

860295-55-2

(3S,4S)-5-[(2S,6R)-6-((2R,3R)-3-Hydroxymethyl-oxiranylmethyl)-3,6-dihydro-2H-pyran-2-yl]-4-methoxy-3-methyl-pentan-2-ol

860295-61-0

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-trimethylsilanyloxy-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester

860295-54-1

(E)-4-[(2R,6S)-6-((2S,3S)-4-Hydroxy-2-methoxy-3-methyl-pentyl)-5,6-dihydro-2H-pyran-2-yl]-but-2-enal

860295-61-0

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-trimethylsilanyloxy-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester

860295-63-2

(3S,4S)-5-[(2S,6R)-6-((E)-4-Hydroxy-but-2-enyl)-3,6-dihydro-2H-pyran-2-yl]-4-methoxy-3-methyl-pentan-2-ol

860295-61-0

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-trimethylsilanyloxy-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester

618096-06-3

(3S,4S)-5-((2S,6R)-6-Allyl-3,6-dihydro-2H-pyran-2-yl)-4-methoxy-3-methyl-pentan-2-ol

860295-61-0

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-trimethylsilanyloxy-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester

860295-56-3

(R)-3-Hydroxy-4-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-pentyl)-5,6-dihydro-2H-pyran-2-yl]-butyraldehyde

860295-61-0

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-trimethylsilanyloxy-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester

860295-64-3

(E)-(S)-5-Hydroxy-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-pentyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester

860295-61-0

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-trimethylsilanyloxy-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester

上游原料

(2S,3R)-3-[(2R,6S)-6-((2S,3R)-2-Methoxy-3-methyl-4-oxo-pentyl)-5,6-dihydro-2H-pyran-2-ylmethyl]-oxirane-2-carbaldehyde (R)-3-Hydroxy-4-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-pentyl)-5,6-dihydro-2H-pyran-2-yl]-butyraldehyde (E)-(S)-5-Hydroxy-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-pentyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester (3S,4S)-5-[(2S,6R)-6-((2R,3R)-3-Hydroxymethyl-oxiranylmethyl)-3,6-dihydro-2H-pyran-2-yl]-4-methoxy-3-methyl-pentan-2-ol (E)-4-[(2R,6S)-6-((2S,3S)-4-Hydroxy-2-methoxy-3-methyl-pentyl)-5,6-dihydro-2H-pyran-2-yl]-but-2-enal (3S,4S)-5-[(2S,6R)-6-((E)-4-Hydroxy-but-2-enyl)-3,6-dihydro-2H-pyran-2-yl]-4-methoxy-3-methyl-pentan-2-ol (3S,4S)-5-((2S,6R)-6-Allyl-3,6-dihydro-2H-pyran-2-yl)-4-methoxy-3-methyl-pentan-2-ol

下游产品

5-(tert-butyl-dimethyl-silanyloxy)-6-{6-[4,6-dihydroxy-2-methoxy-8-(4-methoxy-benzyloxy)-10-methoxymethoxy-13-(4-methoxy-6-methyl-tetrahydro-pyran-2-yl)-3,7,9,11-tetramethyl-tridecyl]-5,6-dihydro-2H-pyran-2-yl}-2-methyl-hex-2-enoic acid methyl ester