百科

(3Z,5E,11Z)-(7R,8S,13S,14R,15S,17S,20R,21R,22S)-8,14,20-Tris-(tert-butyl-dimethyl-silanyloxy)-7,13,15,17,21-pentamethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11-triene-2,10-dione

CAS号：860477-23-2

英文名：(3Z,5E,11Z)-(7R,8S,13S,14R,15S,17S,20R,21R,22S)-8,14,20-Tris-(tert-butyl-dimethyl-silanyloxy)-7,13,15,17,21-pentamethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11-triene-2,10-dione

分子式：C50H92O6Si3

分子量：873.518

合成路线

133007-95-1

(2S,3R,4S)-5-[(4-methoxybenzyl)oxy]-2,4-dimethylpentane-1,3-diol

860477-23-2

(3Z,5E,11Z)-(7R,8S,13S,14R,15S,17S,20R,21R,22S)-8,14,20-Tris-(tert-butyl-dimethyl-silanyloxy)-7,13,15,17,21-pentamethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11-triene-2,10-dione

792911-22-9

(−)-(2S,3R,4S)-3-((tert-butyldimethylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4-dimethylpentan-1-ol

860477-23-2

(3Z,5E,11Z)-(7R,8S,13S,14R,15S,17S,20R,21R,22S)-8,14,20-Tris-(tert-butyl-dimethyl-silanyloxy)-7,13,15,17,21-pentamethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11-triene-2,10-dione

860477-30-1

(E)-(3S,4R)-3-(tert-Butyl-dimethyl-silanyloxy)-6-iodo-4-methyl-hex-5-enal

860477-23-2

(3Z,5E,11Z)-(7R,8S,13S,14R,15S,17S,20R,21R,22S)-8,14,20-Tris-(tert-butyl-dimethyl-silanyloxy)-7,13,15,17,21-pentamethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11-triene-2,10-dione

860477-29-8

(E)-(3S,4R)-3-(tert-Butyl-dimethyl-silanyloxy)-6-iodo-4-methyl-hex-5-en-1-ol

860477-23-2

(3Z,5E,11Z)-(7R,8S,13S,14R,15S,17S,20R,21R,22S)-8,14,20-Tris-(tert-butyl-dimethyl-silanyloxy)-7,13,15,17,21-pentamethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11-triene-2,10-dione

860477-26-5

[(Z)-(3S,4S,5S)-2-Hydroxy-4-(4-methoxy-benzyloxy)-3,5-dimethyl-nona-6,8-dienyl]-phosphonic acid dimethyl ester

860477-23-2

(3Z,5E,11Z)-(7R,8S,13S,14R,15S,17S,20R,21R,22S)-8,14,20-Tris-(tert-butyl-dimethyl-silanyloxy)-7,13,15,17,21-pentamethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11-triene-2,10-dione

792921-75-6

(2R,4S,5R,6S)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethylheptan-1-ol

860477-23-2

(3Z,5E,11Z)-(7R,8S,13S,14R,15S,17S,20R,21R,22S)-8,14,20-Tris-(tert-butyl-dimethyl-silanyloxy)-7,13,15,17,21-pentamethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11-triene-2,10-dione

792911-21-8

(2S,3S,4S)-1,3-bis[(tert-butyldimethylsilyl)oxy]-5-[(4-Methoxybenzyl)oxy]-2,4-dimethylpentane

860477-23-2

(3Z,5E,11Z)-(7R,8S,13S,14R,15S,17S,20R,21R,22S)-8,14,20-Tris-(tert-butyl-dimethyl-silanyloxy)-7,13,15,17,21-pentamethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11-triene-2,10-dione

792911-25-2

(2S,3R,4S,6S,9R,10S,11S,12S,Z)-3-(tert-butyldimethylsilyloxy)-2,4,6,10,12-pentamethylhexadeca-13,15-diene-1,9,11-triol

860477-23-2

(3Z,5E,11Z)-(7R,8S,13S,14R,15S,17S,20R,21R,22S)-8,14,20-Tris-(tert-butyl-dimethyl-silanyloxy)-7,13,15,17,21-pentamethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11-triene-2,10-dione

792911-23-0

(2R,4S,5R,6S)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-N-((1S,2S)-1-hydroxy-1-phenylpropan-2-yl)-N,2,4,6-tetramethylheptanamide

860477-23-2

(3Z,5E,11Z)-(7R,8S,13S,14R,15S,17S,20R,21R,22S)-8,14,20-Tris-(tert-butyl-dimethyl-silanyloxy)-7,13,15,17,21-pentamethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11-triene-2,10-dione

792911-27-4

(Z)-(2S,3R,4S,6S,9R,10R,11S,12S)-3,9-Bis-(tert-butyl-dimethyl-silanyloxy)-2,4,6,10,12-pentamethyl-hexadeca-13,15-diene-1,11-diol

860477-23-2

(3Z,5E,11Z)-(7R,8S,13S,14R,15S,17S,20R,21R,22S)-8,14,20-Tris-(tert-butyl-dimethyl-silanyloxy)-7,13,15,17,21-pentamethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11-triene-2,10-dione

上游原料

(E)-(3S,4R)-3-(tert-Butyl-dimethyl-silanyloxy)-6-iodo-4-methyl-hex-5-en-1-ol (2R,4S,5R,6S)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethylheptan-1-ol (−)-(2S,3R,4S)-3-((tert-butyldimethylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4-dimethylpentan-1-ol (Z)-(2S,3R,4S,6S,9R,10R,11S,12S)-3,9-Bis-(tert-butyl-dimethyl-silanyloxy)-2,4,6,10,12-pentamethyl-hexadeca-13,15-diene-1,11-diol [(Z)-(3S,4S,5S)-2-Hydroxy-4-(4-methoxy-benzyloxy)-3,5-dimethyl-nona-6,8-dienyl]-phosphonic acid dimethyl ester (2S,3R,4S,6S,9R,10S,11S,12S,Z)-3-(tert-butyldimethylsilyloxy)-2,4,6,10,12-pentamethylhexadeca-13,15-diene-1,9,11-triol (2S,3S,4S)-1,3-bis[(tert-butyldimethylsilyl)oxy]-5-[(4-Methoxybenzyl)oxy]-2,4-dimethylpentane (Z)-(5S,6S,7R,8R,11S,13S,14R,15S)-8,14,16-Tris-(tert-butyl-dimethyl-silanyloxy)-5,7,11,13,15-pentamethyl-hexadeca-1,3-dien-6-ol (2R,4S,5R,6S)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-N-((1S,2S)-1-hydroxy-1-phenylpropan-2-yl)-N,2,4,6-tetramethylheptanamide tert-Butyl-[(1S,2S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2-methyl-propoxy]-dimethyl-silane (E)-(3S,4R)-3-(tert-Butyl-dimethyl-silanyloxy)-6-iodo-4-methyl-hex-5-enal (3Z,9E)-(5S,6S,7R,11R,13S,14R,15S)-14-(tert-Butyl-dimethyl-silanyloxy)-6,16-bis-(4-methoxy-benzyloxy)-5,7,11,13,15-pentamethyl-hexadeca-1,3,9-trien-8-one (2S,3R,4S)-5-[(4-methoxybenzyl)oxy]-2,4-dimethylpentane-1,3-diol (+)-(Z)-(2R,3S,4S)-3-(4-methoxybenzyloxy)-2,4-dimethylocta-5,7-dienal

下游产品

(3Z,5E,11Z)-(7R,8S,10S,13S,14R,15S,17S,20R,21R,22S)-8,14,20-Tris-(tert-butyl-dimethyl-silanyloxy)-10-hydroxy-7,13,15,17,21-pentamethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11-trien-2-one (3Z,5E,7R,8S,10R,11Z,13S,14R,15S,17S,20R,21R,22S)-8,14,20-tris((tert-butyldimethylsilyl)oxy)-22-((S,Z)-hexa-3,5-dien-2-yl)-10-hydroxy-7,13,15,17,21-pentamethyloxacyclodocosa-3,5,11-trien-2-one (3Z,5E,7R,8S,10S,11Z,13S,14R,15S,17S,20R,21R,22S)-8,14,20-tris((tert-butyldimethylsilyl)oxy)-22-((S,Z)-hexa-3,5-dien-2-yl)-10-methoxy-7,13,15,17,21-pentamethyloxacyclodocosa-3,5,11-trien-2-one