百科

methyl (2aR,2a1R,3R,4R,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3R,4R,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

CAS号：861114-05-8

英文名：methyl (2aR,2a1R,3R,4R,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

分子式：C30H52O12Si2

分子量：660.898

合成路线

methyl (2aR,2a1R,3R,4S,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-(formyloxy)-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3R,4S,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-(formyloxy)-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3R,4R,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3R,4R,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

dimethyl (2aR,2a1R,3R,4S,4aR,5S,7aS,8S,10R,10aS)-3-acetoxy-4,5-dihydroxy-4-methyl-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-5,10a(8H)-dicarboxylate

dimethyl (2aR,2a1R,3R,4S,4aR,5S,7aS,8S,10R,10aS)-3-acetoxy-4,5-dihydroxy-4-methyl-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-5,10a(8H)-dicarboxylate

methyl (2aR,2a1R,3R,4R,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3R,4R,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

上游原料

methyl (2aR,2a1R,3R,4S,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-(formyloxy)-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate dimethyl (2aR,2a1R,3R,4S,4aR,5S,7aS,8S,10R,10aS)-3-acetoxy-4,5-dihydroxy-4-methyl-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-5,10a(8H)-dicarboxylate

下游产品

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate