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(2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one

(2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one

CAS号：861676-01-9

英文名：(2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one

分子式：C28H48O4Si

分子量：476.764

合成路线

(2S,4R,5R/S,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-ol

(2S,4R,5R/S,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-ol

(2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one

(2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one

(2R,4S)-5-(4-methoxybenzyloxy)-2,4-dimethylpentanal

(2R,4S)-5-(4-methoxybenzyloxy)-2,4-dimethylpentanal

(2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one

(2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one

(2R,4S)-5-(4-methoxybenzyloxy)-N-methoxy-N,2,4-trimethylpentanamide

(2R,4S)-5-(4-methoxybenzyloxy)-N-methoxy-N,2,4-trimethylpentanamide

(2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one

(2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one

(3R,5S)-3,5-dimethyltetrahydro-2H-pyran-2-one

(3R,5S)-3,5-dimethyltetrahydro-2H-pyran-2-one

(2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one

(2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one

tert-Butyl-((E)-(1R,2R)-1-ethyl-4-iodo-2-methyl-but-3-enyloxy)-dimethyl-silane

tert-Butyl-((E)-(1R,2R)-1-ethyl-4-iodo-2-methyl-but-3-enyloxy)-dimethyl-silane

(2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one

(2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one

(2R,4S)-5-hydroxy-N-methoxy-N,2,4-trimethylpentanamide

(2R,4S)-5-hydroxy-N-methoxy-N,2,4-trimethylpentanamide

(2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one

(2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one

上游原料

(2R,4S)-5-hydroxy-N-methoxy-N,2,4-trimethylpentanamide (2R,4S)-5-(4-methoxybenzyloxy)-N-methoxy-N,2,4-trimethylpentanamide tert-Butyl-((E)-(1R,2R)-1-ethyl-4-iodo-2-methyl-but-3-enyloxy)-dimethyl-silane (2R,4S)-5-(4-methoxybenzyloxy)-2,4-dimethylpentanal (2S,4R,5R/S,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-ol (3R,5S)-3,5-dimethyltetrahydro-2H-pyran-2-one

下游产品

(E)-(2S,4R,8R,9R)-9-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-2,4,8-trimethyl-undec-6-en-5-one