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(3S,4R,5S)-4,8-bis(tert-butyldimethylsilyloxy)-3,5-dimethyloct-1-yne

(3S,4R,5S)-4,8-bis(tert-butyldimethylsilyloxy)-3,5-dimethyloct-1-yne

CAS号：861821-96-7

英文名：(3S,4R,5S)-4,8-bis(tert-butyldimethylsilyloxy)-3,5-dimethyloct-1-yne

分子式：C22H46O2Si2

分子量：398.77

合成路线

ethyl (4S,5R,6S,2E)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylhept-2-enoate

ethyl (4S,5R,6S,2E)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylhept-2-enoate

(3S,4R,5S)-4,8-bis(tert-butyldimethylsilyloxy)-3,5-dimethyloct-1-yne

(3S,4R,5S)-4,8-bis(tert-butyldimethylsilyloxy)-3,5-dimethyloct-1-yne

(2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptan-1-ol

(2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptan-1-ol

(3S,4R,5S)-4,8-bis(tert-butyldimethylsilyloxy)-3,5-dimethyloct-1-yne

(3S,4R,5S)-4,8-bis(tert-butyldimethylsilyloxy)-3,5-dimethyloct-1-yne

(4S,5R,6S)-7-(methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylheptan-1-ol

(4S,5R,6S)-7-(methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylheptan-1-ol

(3S,4R,5S)-4,8-bis(tert-butyldimethylsilyloxy)-3,5-dimethyloct-1-yne

(3S,4R,5S)-4,8-bis(tert-butyldimethylsilyloxy)-3,5-dimethyloct-1-yne

ethyl (4S,5R,6S)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylheptanoate

ethyl (4S,5R,6S)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylheptanoate

(3S,4R,5S)-4,8-bis(tert-butyldimethylsilyloxy)-3,5-dimethyloct-1-yne

(3S,4R,5S)-4,8-bis(tert-butyldimethylsilyloxy)-3,5-dimethyloct-1-yne

1-((2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptyloxy)methyl-4-methoxybenzene

1-((2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptyloxy)methyl-4-methoxybenzene

(3S,4R,5S)-4,8-bis(tert-butyldimethylsilyloxy)-3,5-dimethyloct-1-yne

(3S,4R,5S)-4,8-bis(tert-butyldimethylsilyloxy)-3,5-dimethyloct-1-yne

上游原料

(2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptan-1-ol ethyl (4S,5R,6S)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylheptanoate ethyl (4S,5R,6S,2E)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylhept-2-enoate (4S,5R,6S)-7-(methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylheptan-1-ol 1-((2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptyloxy)methyl-4-methoxybenzene

下游产品

(2R,4E,8S,9R,10S,11Z,13S,15S,16R,17E)-9,15-bis(tert-butyldimethylsilyloxy)-13-(tert-butyldimethylsilyloxy)-2-((4S,5S)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-8,10,16-trimethyl-19-(trityloxy)nonadeca-4,11,17-trien-3-one