百科

(4R,5S,7S,10S,11R,12S,E)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-(trityloxy)pentadec-2-en-8-yn-7-ol

(4R,5S,7S,10S,11R,12S,E)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-(trityloxy)pentadec-2-en-8-yn-7-ol

CAS号：861822-06-2

英文名：(4R,5S,7S,10S,11R,12S,E)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-(trityloxy)pentadec-2-en-8-yn-7-ol

分子式：C55H88O5Si3

分子量：913.541

合成路线

(4S,5R,6S)-7-(methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylheptan-1-ol

(4S,5R,6S)-7-(methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylheptan-1-ol

(4R,5S,7S,10S,11R,12S,E)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-(trityloxy)pentadec-2-en-8-yn-7-ol

(4R,5S,7S,10S,11R,12S,E)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-(trityloxy)pentadec-2-en-8-yn-7-ol

(2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptan-1-ol

(2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptan-1-ol

(4R,5S,7S,10S,11R,12S,E)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-(trityloxy)pentadec-2-en-8-yn-7-ol

(4R,5S,7S,10S,11R,12S,E)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-(trityloxy)pentadec-2-en-8-yn-7-ol

ethyl (4S,5R,6S,2E)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylhept-2-enoate

ethyl (4S,5R,6S,2E)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylhept-2-enoate

(4R,5S,7S,10S,11R,12S,E)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-(trityloxy)pentadec-2-en-8-yn-7-ol

(4R,5S,7S,10S,11R,12S,E)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-(trityloxy)pentadec-2-en-8-yn-7-ol

ethyl (4S,5R,6S)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylheptanoate

ethyl (4S,5R,6S)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylheptanoate

(4R,5S,7S,10S,11R,12S,E)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-(trityloxy)pentadec-2-en-8-yn-7-ol

(4R,5S,7S,10S,11R,12S,E)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-(trityloxy)pentadec-2-en-8-yn-7-ol

1-((2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptyloxy)methyl-4-methoxybenzene

1-((2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptyloxy)methyl-4-methoxybenzene

(4R,5S,7S,10S,11R,12S,E)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-(trityloxy)pentadec-2-en-8-yn-7-ol

(4R,5S,7S,10S,11R,12S,E)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-(trityloxy)pentadec-2-en-8-yn-7-ol

上游原料

(2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptan-1-ol ethyl (4S,5R,6S)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylheptanoate ethyl (4S,5R,6S,2E)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylhept-2-enoate (4S,5R,6S)-7-(methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-4,6-dimethylheptan-1-ol 1-((2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptyloxy)methyl-4-methoxybenzene

下游产品

(2R,4E,8S,9R,10S,11Z,13S,15S,16R,17E)-9,15-bis(tert-butyldimethylsilyloxy)-13-(tert-butyldimethylsilyloxy)-2-((4S,5S)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-8,10,16-trimethyl-19-(trityloxy)nonadeca-4,11,17-trien-3-one