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(3R,7S,10R,11S,12R)-13-Benzyloxy-3,11-bis-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-10,12-dimethyl-tridec-1-en-5-one

(3R,7S,10R,11S,12R)-13-Benzyloxy-3,11-bis-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-10,12-dimethyl-tridec-1-en-5-one

CAS号：862096-24-0

英文名：(3R,7S,10R,11S,12R)-13-Benzyloxy-3,11-bis-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-10,12-dimethyl-tridec-1-en-5-one

分子式：C42H70O6Si2

分子量：727.173

合成路线

[(1S,2R,5S)-1-((R)-2-Benzyloxy-1-methyl-ethyl)-5-(4-methoxy-benzyloxy)-2,7-dimethyl-oct-7-enyloxy]-tert-butyl-dimethyl-silane

[(1S,2R,5S)-1-((R)-2-Benzyloxy-1-methyl-ethyl)-5-(4-methoxy-benzyloxy)-2,7-dimethyl-oct-7-enyloxy]-tert-butyl-dimethyl-silane

(3R,7S,10R,11S,12R)-13-Benzyloxy-3,11-bis-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-10,12-dimethyl-tridec-1-en-5-one

(3R,7S,10R,11S,12R)-13-Benzyloxy-3,11-bis-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-10,12-dimethyl-tridec-1-en-5-one

(4S,7R,8S,9R)-10-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-2,7,9-trimethyl-dec-1-en-4-ol

(4S,7R,8S,9R)-10-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-2,7,9-trimethyl-dec-1-en-4-ol

(3R,7S,10R,11S,12R)-13-Benzyloxy-3,11-bis-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-10,12-dimethyl-tridec-1-en-5-one

(3R,7S,10R,11S,12R)-13-Benzyloxy-3,11-bis-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-10,12-dimethyl-tridec-1-en-5-one

(4S,7R,8S,9R)-10-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-7,9-dimethyl-decan-2-one

(4S,7R,8S,9R)-10-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-7,9-dimethyl-decan-2-one

(3R,7S,10R,11S,12R)-13-Benzyloxy-3,11-bis-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-10,12-dimethyl-tridec-1-en-5-one

(3R,7S,10R,11S,12R)-13-Benzyloxy-3,11-bis-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-10,12-dimethyl-tridec-1-en-5-one

(2S,3R,4R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentanal

(2S,3R,4R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentanal

(3R,7S,10R,11S,12R)-13-Benzyloxy-3,11-bis-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-10,12-dimethyl-tridec-1-en-5-one

(3R,7S,10R,11S,12R)-13-Benzyloxy-3,11-bis-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-10,12-dimethyl-tridec-1-en-5-one

(4R,5S,6R)-7-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,6-dimethyl-heptanal

(4R,5S,6R)-7-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,6-dimethyl-heptanal

(3R,7S,10R,11S,12R)-13-Benzyloxy-3,11-bis-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-10,12-dimethyl-tridec-1-en-5-one

(3R,7S,10R,11S,12R)-13-Benzyloxy-3,11-bis-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-10,12-dimethyl-tridec-1-en-5-one

上游原料

(4S,7R,8S,9R)-10-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-7,9-dimethyl-decan-2-one (2S,3R,4R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentanal [(1S,2R,5S)-1-((R)-2-Benzyloxy-1-methyl-ethyl)-5-(4-methoxy-benzyloxy)-2,7-dimethyl-oct-7-enyloxy]-tert-butyl-dimethyl-silane (4S,7R,8S,9R)-10-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-2,7,9-trimethyl-dec-1-en-4-ol (4R,5S,6R)-7-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,6-dimethyl-heptanal

下游产品

(3R,7S,10R,11S,12R)-13-Benzyloxy-3,11-bis-(tert-butyl-dimethyl-silanyloxy)-7-hydroxy-10,12-dimethyl-tridec-1-en-5-one (3R,5R,7S,10R,11S,12R)-13-Benzyloxy-3,11-bis-(tert-butyl-dimethyl-silanyloxy)-10,12-dimethyl-tridec-1-ene-5,7-diol