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(2R,4S,6S,8S,10S)-(4-(t-butyldimethylsiloxy)-10-hydroxy-10-methyl-8-{2-[1-methyl-2-(triisopropylsiloxy)-ethyl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetaldehyde
CAS号:862379-38-2
英文名:(2R,4S,6S,8S,10S)-(4-(t-butyldimethylsiloxy)-10-hydroxy-10-methyl-8-{2-[1-methyl-2-(triisopropylsiloxy)-ethyl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetaldehyde
分子式:C33H64O6Si2
分子量:613.029
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合成路线
862379-36-0
(2S,5S)-7-(4-Methoxy-benzyloxy)-2-methyl-5-triethylsilanyloxy-1-triisopropylsilanyloxy-heptan-3-one
862379-38-2
(2R,4S,6S,8S,10S)-(4-(t-butyldimethylsiloxy)-10-hydroxy-10-methyl-8-{2-[1-methyl-2-(triisopropylsiloxy)-ethyl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetaldehyde
158783-84-7
methyl (S)-2-methyl-3-(triisopropylsiloxy)-propionate
862379-38-2
(2R,4S,6S,8S,10S)-(4-(t-butyldimethylsiloxy)-10-hydroxy-10-methyl-8-{2-[1-methyl-2-(triisopropylsiloxy)-ethyl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetaldehyde
158783-85-8
(S)-N-methoxy-N-methyl-3-triisopropylsilanyloxy-2-methylpropionamide
862379-38-2
(2R,4S,6S,8S,10S)-(4-(t-butyldimethylsiloxy)-10-hydroxy-10-methyl-8-{2-[1-methyl-2-(triisopropylsiloxy)-ethyl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetaldehyde
185409-77-2
(5S,7S)-7-(2-(benzyloxy)ethyl)-5-((tert-butyldimethylsilyl)oxy)-9,9-diethyl-3-methylene-1,1-bis((1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)-2,8-dioxa-9-sila-1-boraundecane
862379-38-2
(2R,4S,6S,8S,10S)-(4-(t-butyldimethylsiloxy)-10-hydroxy-10-methyl-8-{2-[1-methyl-2-(triisopropylsiloxy)-ethyl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetaldehyde
185409-71-6
(4S,6S)-8-benzyloxy-4-hydroxy-6-(triethylsiloxy)-2-octanone
862379-38-2
(2R,4S,6S,8S,10S)-(4-(t-butyldimethylsiloxy)-10-hydroxy-10-methyl-8-{2-[1-methyl-2-(triisopropylsiloxy)-ethyl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetaldehyde
199857-49-3
(2S,4S,6R,8S,10S)-8-(2-benzyloxyethyl)-10-(t-butyldimethylsiloxy)-2-{2-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-allyl}-1,7-dioxaspiro[5.5]undecan-4-ol
862379-38-2
(2R,4S,6S,8S,10S)-(4-(t-butyldimethylsiloxy)-10-hydroxy-10-methyl-8-{2-[1-methyl-2-(triisopropylsiloxy)-ethyl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetaldehyde
862379-31-5
(4S)-2-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-6-(p-methoxybenzyloxy)-4-(p-nitrobenzoyloxy)-hex-1-ene
862379-38-2
(2R,4S,6S,8S,10S)-(4-(t-butyldimethylsiloxy)-10-hydroxy-10-methyl-8-{2-[1-methyl-2-(triisopropylsiloxy)-ethyl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetaldehyde
862379-33-7
(2S,6R,8S,10S)-8-(2-Benzyloxy-ethyl)-10-(tert-butyl-dimethyl-silanyloxy)-2-((R)-3-methyl-2-methylene-4-triisopropylsilanyloxy-butyl)-1,7-dioxa-spiro[5.5]undecan-4-one
862379-38-2
(2R,4S,6S,8S,10S)-(4-(t-butyldimethylsiloxy)-10-hydroxy-10-methyl-8-{2-[1-methyl-2-(triisopropylsiloxy)-ethyl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetaldehyde
199857-46-0
(4R)-2-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-6-(p-methoxybenzyloxy)-4-(triethylsiloxy)-hex-1-ene
862379-38-2
(2R,4S,6S,8S,10S)-(4-(t-butyldimethylsiloxy)-10-hydroxy-10-methyl-8-{2-[1-methyl-2-(triisopropylsiloxy)-ethyl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetaldehyde
199857-44-8
(2S,5S)-5-hydroxy-7-(p-methoxybenzyloxy)-2-methyl-1-(triisopropylsiloxy)-heptan-3-one
862379-38-2
(2R,4S,6S,8S,10S)-(4-(t-butyldimethylsiloxy)-10-hydroxy-10-methyl-8-{2-[1-methyl-2-(triisopropylsiloxy)-ethyl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetaldehyde
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上游原料
(5S,7S)-7-(2-(benzyloxy)ethyl)-5-((tert-butyldimethylsilyl)oxy)-9,9-diethyl-3-methylene-1,1-bis((1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)-2,8-dioxa-9-sila-1-boraundecane
(4S,6S)-8-benzyloxy-4-hydroxy-6-(triethylsiloxy)-2-octanone
(3S)-5-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-3-(triethylsiloxy)-hex-5-en-1-ol
(2S,5S)-7-(4-Methoxy-benzyloxy)-2-methyl-5-triethylsilanyloxy-1-triisopropylsilanyloxy-heptan-3-one
methyl (S)-2-methyl-3-(triisopropylsiloxy)-propionate
(2S,4S,6R,8S,10S)-8-(2-benzyloxyethyl)-10-(t-butyldimethylsiloxy)-2-{2-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-allyl}-1,7-dioxaspiro[5.5]undecan-4-ol
(4S)-2-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-6-(p-methoxybenzyloxy)-4-(p-nitrobenzoyloxy)-hex-1-ene
(2S,5S)-5-hydroxy-7-(p-methoxybenzyloxy)-2-methyl-1-(triisopropylsiloxy)-heptan-3-one
(S)-N-methoxy-N-methyl-3-triisopropylsilanyloxy-2-methylpropionamide
(S)-7,7-diisopropyl-4,8-dimethyl-3-methylene-1,1-bis((1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)-2,6-dioxa-7-sila-1-boranonane
(S)-3-methyl-4-(triisopropylsiloxy)-butan-2-one
(2S,6R,8S,10S)-8-(2-Benzyloxy-ethyl)-10-(tert-butyl-dimethyl-silanyloxy)-2-((R)-3-methyl-2-methylene-4-triisopropylsilanyloxy-butyl)-1,7-dioxa-spiro[5.5]undecan-4-one
(4S)-2-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-6-(p-methoxybenzyloxy)-4-(triethylsiloxy)-hex-1-ene
(3S)-5-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-3-(triethylsiloxy)-hex-5-enal
(4R)-2-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-6-(p-methoxybenzyloxy)-4-(triethylsiloxy)-hex-1-ene
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