百科

6-(6-{(3E)(1R,2R)-2-[(4-methoxyphenyl)methoxy]-1-methyl-4-phenylbut-3-enyl}(4S,4S,6S)-2,2,5-trimethyl(1,3-dioxan-4-yl))(5R,6R)-5-(tert-butyldimethylsilyloxy)heptan-3-one

CAS号：862465-61-0

英文名：6-(6-{(3E)(1R,2R)-2-[(4-methoxyphenyl)methoxy]-1-methyl-4-phenylbut-3-enyl}(4S,4S,6S)-2,2,5-trimethyl(1,3-dioxan-4-yl))(5R,6R)-5-(tert-butyldimethylsilyloxy)heptan-3-one

分子式：C39H60O6Si

分子量：652.976

合成路线

862465-76-7

2-(6-{(3E)-(1R,2R)-2-[(4-methoxyphenyl)methoxy]-1-methyl-4-phenylbut-3-enyl}-(4S,5S,6S)-2,2,5-trimethyl(1,3-dioxan-4-yl))(2R)-propan-1-one

862465-61-0

6-(6-{(3E)(1R,2R)-2-[(4-methoxyphenyl)methoxy]-1-methyl-4-phenylbut-3-enyl}(4S,4S,6S)-2,2,5-trimethyl(1,3-dioxan-4-yl))(5R,6R)-5-(tert-butyldimethylsilyloxy)heptan-3-one

862465-73-4

1-(4'R-benzyl-2'-oxo-oxazolidin-3'-yl)-5S-hydroxy-7R-(4-methoxy-benzyloxy)-2R,4S,6R-trimethyl-9-phenyl-non-8-ene-1,3-dione

862465-61-0

6-(6-{(3E)(1R,2R)-2-[(4-methoxyphenyl)methoxy]-1-methyl-4-phenylbut-3-enyl}(4S,4S,6S)-2,2,5-trimethyl(1,3-dioxan-4-yl))(5R,6R)-5-(tert-butyldimethylsilyloxy)heptan-3-one

862465-75-6

4R-benzyl-3-(2'R-{6''S-[2'''R-(4-methoxy-benzyloxy)-1'''R-methyl-4'''-phenyl-but-3'''-enyl]-2'',2'',5''S-trimethyl-[1,3]dioxan-4''S-yl}-propionyl)-oxazolidin-2-one

862465-61-0

6-(6-{(3E)(1R,2R)-2-[(4-methoxyphenyl)methoxy]-1-methyl-4-phenylbut-3-enyl}(4S,4S,6S)-2,2,5-trimethyl(1,3-dioxan-4-yl))(5R,6R)-5-(tert-butyldimethylsilyloxy)heptan-3-one

862465-90-5

1-(4'R-benzyl-2'-oxo-oxazolidin-3'-yl)-7R-(4-methoxy-benzyloxy)-2R,4S,6R-trimethyl-9-phenyl-5S-(triethyl-silanyloxy)-non-8-ene-1,3-dione

862465-61-0

6-(6-{(3E)(1R,2R)-2-[(4-methoxyphenyl)methoxy]-1-methyl-4-phenylbut-3-enyl}(4S,4S,6S)-2,2,5-trimethyl(1,3-dioxan-4-yl))(5R,6R)-5-(tert-butyldimethylsilyloxy)heptan-3-one

862465-74-5

(R)-4-Benzyl-3-[(E)-(2R,3S,4R,5R,6R,7R)-3-hydroxy-7-(4-methoxy-benzyloxy)-2,4,6-trimethyl-9-phenyl-5-triethylsilanyloxy-non-8-enoyl]-oxazolidin-2-one

862465-61-0

6-(6-{(3E)(1R,2R)-2-[(4-methoxyphenyl)methoxy]-1-methyl-4-phenylbut-3-enyl}(4S,4S,6S)-2,2,5-trimethyl(1,3-dioxan-4-yl))(5R,6R)-5-(tert-butyldimethylsilyloxy)heptan-3-one

上游原料

4R-benzyl-3-(2'R-{6''S-[2'''R-(4-methoxy-benzyloxy)-1'''R-methyl-4'''-phenyl-but-3'''-enyl]-2'',2'',5''S-trimethyl-[1,3]dioxan-4''S-yl}-propionyl)-oxazolidin-2-one 2-(6-{(3E)-(1R,2R)-2-[(4-methoxyphenyl)methoxy]-1-methyl-4-phenylbut-3-enyl}-(4S,5S,6S)-2,2,5-trimethyl(1,3-dioxan-4-yl))(2R)-propan-1-one 1-(4'R-benzyl-2'-oxo-oxazolidin-3'-yl)-5S-hydroxy-7R-(4-methoxy-benzyloxy)-2R,4S,6R-trimethyl-9-phenyl-non-8-ene-1,3-dione (R)-4-Benzyl-3-[(E)-(2R,3S,4R,5R,6R,7R)-3-hydroxy-7-(4-methoxy-benzyloxy)-2,4,6-trimethyl-9-phenyl-5-triethylsilanyloxy-non-8-enoyl]-oxazolidin-2-one 1-(4'R-benzyl-2'-oxo-oxazolidin-3'-yl)-7R-(4-methoxy-benzyloxy)-2R,4S,6R-trimethyl-9-phenyl-5S-(triethyl-silanyloxy)-non-8-ene-1,3-dione

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