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(E)-(R)-1-{(2S,5S,2'S,5'R)-5'-[(R)-4-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-butyl]-octahydro-[2,2']bifuranyl-5-yl}-undec-4-en-1-ol

(E)-(R)-1-{(2S,5S,2'S,5'R)-5'-[(R)-4-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-butyl]-octahydro-[2,2']bifuranyl-5-yl}-undec-4-en-1-ol

CAS号：862557-38-8

英文名：(E)-(R)-1-{(2S,5S,2'S,5'R)-5'-[(R)-4-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-butyl]-octahydro-[2,2']bifuranyl-5-yl}-undec-4-en-1-ol

分子式：C36H62O5Si

分子量：602.96

合成路线

(2R,2'S,5'S,2''S,5''R)-5''-((R)-4-Benzyloxy-1-hydroxy-butyl)-hexahydro-[2,2';5',2'']terfuran-5-one

(2R,2'S,5'S,2''S,5''R)-5''-((R)-4-Benzyloxy-1-hydroxy-butyl)-hexahydro-[2,2';5',2'']terfuran-5-one

(E)-(R)-1-{(2S,5S,2'S,5'R)-5'-[(R)-4-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-butyl]-octahydro-[2,2']bifuranyl-5-yl}-undec-4-en-1-ol

(E)-(R)-1-{(2S,5S,2'S,5'R)-5'-[(R)-4-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-butyl]-octahydro-[2,2']bifuranyl-5-yl}-undec-4-en-1-ol

(4E,8E)-dodeca-4,8-diene-1,12-diol

(4E,8E)-dodeca-4,8-diene-1,12-diol

(E)-(R)-1-{(2S,5S,2'S,5'R)-5'-[(R)-4-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-butyl]-octahydro-[2,2']bifuranyl-5-yl}-undec-4-en-1-ol

(E)-(R)-1-{(2S,5S,2'S,5'R)-5'-[(R)-4-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-butyl]-octahydro-[2,2']bifuranyl-5-yl}-undec-4-en-1-ol

(4E,8E)-dodeca-4,8-dienedial

(4E,8E)-dodeca-4,8-dienedial

(E)-(R)-1-{(2S,5S,2'S,5'R)-5'-[(R)-4-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-butyl]-octahydro-[2,2']bifuranyl-5-yl}-undec-4-en-1-ol

(E)-(R)-1-{(2S,5S,2'S,5'R)-5'-[(R)-4-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-butyl]-octahydro-[2,2']bifuranyl-5-yl}-undec-4-en-1-ol

上游原料

(4E,8E)-dodeca-4,8-diene-1,12-diol (2R,2'S,5'S,2''S,5''R)-5''-((R)-4-Benzyloxy-1-hydroxy-butyl)-hexahydro-[2,2';5',2'']terfuran-5-one (4E,8E)-dodeca-4,8-dienedial

下游产品

(R)-4-(tert-Butyl-dimethyl-silanyloxy)-4-{(2S,5R,2'S,5'S)-5'-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-butyraldehyde (4R,5R,8S,9S,12S,13R)-4,13-di-tert-butyldimethylsilyloxy-5:8,9:12-dioxido-tricosan-1-ol (5R,8R,9S,1OS,13S,14R)-5,14-di-tert-butyldimethylsilyloxy-6:9,10:13-dioxido-tetracos-1-ene