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(1S,5R,6S)-5-Hydroxy-3-hydroxymethyl-4-((E)-propenyl)-7-oxa-bicyclo[4.1.0]hept-3-en-2-one

(1S,5R,6S)-5-Hydroxy-3-hydroxymethyl-4-((E)-propenyl)-7-oxa-bicyclo[4.1.0]hept-3-en-2-one

CAS号：862593-57-5

英文名：(1S,5R,6S)-5-Hydroxy-3-hydroxymethyl-4-((E)-propenyl)-7-oxa-bicyclo[4.1.0]hept-3-en-2-one

分子式：C10H12O4

分子量：196.2

合成路线

(1S,6R)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-5',5'-diethyl-4-((E)-prop-1-en-1-yl)-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

(1S,6R)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-5',5'-diethyl-4-((E)-prop-1-en-1-yl)-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

(1S,5R,6S)-5-Hydroxy-3-hydroxymethyl-4-((E)-propenyl)-7-oxa-bicyclo[4.1.0]hept-3-en-2-one

(1S,5R,6S)-5-Hydroxy-3-hydroxymethyl-4-((E)-propenyl)-7-oxa-bicyclo[4.1.0]hept-3-en-2-one

(1S,5R,6S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-5-hydroxy-4-((E)-propenyl)-7-oxa-bicyclo[4.1.0]hept-3-en-2-one

(1S,5R,6S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-5-hydroxy-4-((E)-propenyl)-7-oxa-bicyclo[4.1.0]hept-3-en-2-one

(1S,5R,6S)-5-Hydroxy-3-hydroxymethyl-4-((E)-propenyl)-7-oxa-bicyclo[4.1.0]hept-3-en-2-one

(1S,5R,6S)-5-Hydroxy-3-hydroxymethyl-4-((E)-propenyl)-7-oxa-bicyclo[4.1.0]hept-3-en-2-one

(1S,6R)-4-bromo-3-(((tert-butyldiphenylsilyl)oxy)methyl)-5',5'-diethyl-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

(1S,6R)-4-bromo-3-(((tert-butyldiphenylsilyl)oxy)methyl)-5',5'-diethyl-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

(1S,5R,6S)-5-Hydroxy-3-hydroxymethyl-4-((E)-propenyl)-7-oxa-bicyclo[4.1.0]hept-3-en-2-one

(1S,5R,6S)-5-Hydroxy-3-hydroxymethyl-4-((E)-propenyl)-7-oxa-bicyclo[4.1.0]hept-3-en-2-one

上游原料

(1S,5R,6S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-5-hydroxy-4-((E)-propenyl)-7-oxa-bicyclo[4.1.0]hept-3-en-2-one (1S,6R)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-5',5'-diethyl-4-((E)-prop-1-en-1-yl)-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one (1S,6R)-4-bromo-3-(((tert-butyldiphenylsilyl)oxy)methyl)-5',5'-diethyl-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

下游产品

(1aS,2R,4S,6R,7aS)-2-Hydroxy-6-[(1S,5R,6S)-5-hydroxy-2-oxo-4-((E)-propenyl)-7-oxa-bicyclo[4.1.0]hept-3-en-3-ylmethoxy]-4-methyl-1a,2,6,7a-tetrahydro-1,5-dioxa-cyclopropa[b]naphthalene-3,7-dione (1aS,2R,7aS)-2-Hydroxy-4-methyl-1a,2,4,7a-tetrahydro-1,5-dioxa-cyclopropa[b]naphthalen-7-one