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(3S,4S)-6-(tert-Butyl-diphenyl-silanyloxy)-hexane-1,3,4-triol

(3S,4S)-6-(tert-Butyl-diphenyl-silanyloxy)-hexane-1,3,4-triol

CAS号：862603-54-1

英文名：(3S,4S)-6-(tert-Butyl-diphenyl-silanyloxy)-hexane-1,3,4-triol

分子式：C22H32O4Si

分子量：388.573

合成路线

(E)-6-(tert-Butyl-diphenyl-silanyloxy)-hex-3-enoic acid methyl ester

(E)-6-(tert-Butyl-diphenyl-silanyloxy)-hex-3-enoic acid methyl ester

(3S,4S)-6-(tert-Butyl-diphenyl-silanyloxy)-hexane-1,3,4-triol

(3S,4S)-6-(tert-Butyl-diphenyl-silanyloxy)-hexane-1,3,4-triol

上游原料

(E)-6-(tert-Butyl-diphenyl-silanyloxy)-hex-3-enoic acid methyl ester

下游产品

(S)-3-((R)-13-{(2S,5R,2'S,5'R)-5'-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-13-hydroxy-tridecyl)-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one Toluene-4-sulfonic acid (S)-3-((2S,4S)-2-phenyl-[1,3]dioxan-4-yl)-3-[(E)-2-((S)-toluene-4-sulfinyl)-vinyloxy]-propyl ester (2R,5S)-5-((2S,4S)-2-Phenyl-[1,3]dioxan-4-yl)-tetrahydro-furan-2-carbaldehyde (S)-3-((2R,11R)-2-(tert-Butyl-dimethyl-silanyloxy)-11-{(2S,5R,2'S,5'R)-5'-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-11-hydroxy-undecyl)-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one (S)-3-((E)-(2R,13R)-2-(tert-Butyl-dimethyl-silanyloxy)-13-{(2S,5R,2'S,5'R)-5'-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-13-hydroxy-tridec-10-enyl)-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one tert-Butyl-[(S)-1-((2R,5S)-5-{(S)-3-iodo-1-[(E)-2-((S)-toluene-4-sulfinyl)-vinyloxy]-propyl}-tetrahydro-furan-2-yl)-undecyloxy]-dimethyl-silane (S)-3-((2R,13R)-2-(tert-Butyl-dimethyl-silanyloxy)-13-{(2S,5R,2'S,5'R)-5'-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-13-hydroxy-tridecyl)-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one (S)-3-((2R,11R)-2-(tert-Butyl-dimethyl-silanyloxy)-11-{(2S,5R,2'S,5'R)-5'-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-11-hydroxy-undecyl)-5-methyl-5H-furan-2-one (2S,5R,2'S,5'R)-5'-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-carbaldehyde (S)-3-((R)-13-{(2S,5R,2'S,5'R)-5'-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-13-hydroxy-tridecyl)-5-methyl-5H-furan-2-one (S)-1-((2S,4S)-2-Phenyl-[1,3]dioxan-4-yl)-propane-1,3-diol (S)-1-{(2S,5R)-5-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-undecyl]-tetrahydro-furan-2-yl}-propane-1,3-diol (S)-3-((E)-(2R,11R)-2-(tert-Butyl-dimethyl-silanyloxy)-11-{(2S,5R,2'S,5'R)-5'-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-11-hydroxy-undec-8-enyl)-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one Toluene-4-sulfonic acid (S)-3-{(2S,5R)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-undecyl]-tetrahydro-furan-2-yl}-3-[(E)-2-((S)-toluene-4-sulfinyl)-vinyloxy]-propyl ester tert-Butyl-dimethyl-{(S)-1-[(2S,5R,2'S,5'R)-5'-((S)-toluene-4-sulfinylmethyl)-octahydro-[2,2']bifuranyl-5-yl]-undecyloxy}-silane tert-Butyl-dimethyl-{(S)-1-[(2R,5S)-5-((2S,4S)-2-phenyl-[1,3]dioxan-4-yl)-tetrahydro-furan-2-yl]-undecyloxy}-silane (2S,4S)-4-{(S)-3-Iodo-1-[(E)-2-((S)-toluene-4-sulfinyl)-vinyloxy]-propyl}-2-phenyl-[1,3]dioxane