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(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

CAS号：862736-26-3

英文名：(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

分子式：C29H40O3Si

分子量：464.712

合成路线

(2R,5S,6S)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-5-methyl-tetrahydro-pyran-2-carboxylic acid methyl ester

(2R,5S,6S)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-5-methyl-tetrahydro-pyran-2-carboxylic acid methyl ester

(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

(Z)-(2S,3S)-3-(dimethyl-phenyl-silanyl)-2-hydroxy-hex-4-enoic acid methyl ester

(Z)-(2S,3S)-3-(dimethyl-phenyl-silanyl)-2-hydroxy-hex-4-enoic acid methyl ester

(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

(2S,3S)-3-(dimethyl-phenyl-silanyl)-2-hydroxy-hex-4-ynoic acid methyl ester

(2S,3S)-3-(dimethyl-phenyl-silanyl)-2-hydroxy-hex-4-ynoic acid methyl ester

(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

(Z)-(2S,3S)-3-(dimethyl-phenyl-silanyl)-2-trimethylsilanyloxy-hex-4-enoic acid methyl ester

(Z)-(2S,3S)-3-(dimethyl-phenyl-silanyl)-2-trimethylsilanyloxy-hex-4-enoic acid methyl ester

(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

(2R,5S,6S)-6-(2-hydroxy-ethyl)-5-methyl-tetrahydro-pyran-2-carboxylic acid methyl ester

(2R,5S,6S)-6-(2-hydroxy-ethyl)-5-methyl-tetrahydro-pyran-2-carboxylic acid methyl ester

(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

{(2R,5S,6S)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-5-methyl-tetrahydro-pyran-2-yl}-methanol

{(2R,5S,6S)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-5-methyl-tetrahydro-pyran-2-yl}-methanol

(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

tert-butyl (2-((2S,3S,6R)-6-(iodomethyl)-3-methyltetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

tert-butyl (2-((2S,3S,6R)-6-(iodomethyl)-3-methyltetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

(E)-1-((2R,5S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)pent-3-en-2-one

上游原料

(2R,5S,6S)-6-(2-hydroxy-ethyl)-5-methyl-tetrahydro-pyran-2-carboxylic acid methyl ester (2R,5S,6S)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-5-methyl-tetrahydro-pyran-2-carboxylic acid methyl ester (Z)-(2S,3S)-3-(dimethyl-phenyl-silanyl)-2-trimethylsilanyloxy-hex-4-enoic acid methyl ester tert-butyl (2-((2S,3S,6R)-6-(iodomethyl)-3-methyltetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane (Z)-(2S,3S)-3-(dimethyl-phenyl-silanyl)-2-hydroxy-hex-4-enoic acid methyl ester (2S,3S)-3-(dimethyl-phenyl-silanyl)-2-hydroxy-hex-4-ynoic acid methyl ester {(2R,5S,6S)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-5-methyl-tetrahydro-pyran-2-yl}-methanol

下游产品

2-((2S,3S,6R)-3-methyl-6-((E)-2-oxopent-3-enyl)tetrahydro-2H-pyran-2-yl)acetic acid