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(4R,5R)-5-Hydroxymethyl-4-(R)-oxiranyl-dihydro-furan-2-one

(4R,5R)-5-Hydroxymethyl-4-(R)-oxiranyl-dihydro-furan-2-one

CAS号：86277-78-3

英文名：(4R,5R)-5-Hydroxymethyl-4-(R)-oxiranyl-dihydro-furan-2-one

分子式：C7H10O4

分子量：158.152

合成路线

[(3aR,5S,6R,6aR)-2,2-Dimethyl-5-(toluene-4-sulfonyloxymethyl)-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-acetic acid methyl ester

[(3aR,5S,6R,6aR)-2,2-Dimethyl-5-(toluene-4-sulfonyloxymethyl)-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-acetic acid methyl ester

(4R,5R)-5-Hydroxymethyl-4-(R)-oxiranyl-dihydro-furan-2-one

(4R,5R)-5-Hydroxymethyl-4-(R)-oxiranyl-dihydro-furan-2-one

Toluene-4-sulfonic acid (R)-2-hydroxy-2-((2R,3R)-2-hydroxymethyl-5-oxo-tetrahydro-furan-3-yl)-ethyl ester

Toluene-4-sulfonic acid (R)-2-hydroxy-2-((2R,3R)-2-hydroxymethyl-5-oxo-tetrahydro-furan-3-yl)-ethyl ester

(4R,5R)-5-Hydroxymethyl-4-(R)-oxiranyl-dihydro-furan-2-one

(4R,5R)-5-Hydroxymethyl-4-(R)-oxiranyl-dihydro-furan-2-one

3-deoxy-1,2-O-isopropylidene-3-C-(methoxycarbonylmethyl)-α-D-ribofuranose

3-deoxy-1,2-O-isopropylidene-3-C-(methoxycarbonylmethyl)-α-D-ribofuranose

(4R,5R)-5-Hydroxymethyl-4-(R)-oxiranyl-dihydro-furan-2-one

(4R,5R)-5-Hydroxymethyl-4-(R)-oxiranyl-dihydro-furan-2-one

上游原料

3-deoxy-1,2-O-isopropylidene-3-C-(methoxycarbonylmethyl)-α-D-ribofuranose [(3aR,5S,6R,6aR)-2,2-Dimethyl-5-(toluene-4-sulfonyloxymethyl)-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-acetic acid methyl ester Toluene-4-sulfonic acid (R)-2-hydroxy-2-((2R,3R)-2-hydroxymethyl-5-oxo-tetrahydro-furan-3-yl)-ethyl ester

下游产品

(3R,4S)-3-Allyl-4-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-hex-5-enoic acid methyl ester (2R,3R)-2-hydroxymethyl-3-vinyl-γ-butyrolactone (4R,5S,6S)-4-Allyl-6-methyl-5-vinyl-tetrahydro-pyran-2-one (2S,3S,4R)-4-((E)-2-Methoxy-vinyl)-3-vinyl-hept-6-en-2-ol (4S,5S,6S)-4-Allyl-3-[1-dimethylamino-meth-(Z)-ylidene]-6-methyl-5-vinyl-tetrahydro-pyran-2-one (3S,4S,5S)-3-Allyl-5-methyl-4-vinyl-dihydro-furan-2-one