百科

(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-diphenyl-silanyloxy)-3-methoxy-18-methyl-13-((E)-4-methyl-pent-1-enyl)-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-ol

(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-diphenyl-silanyloxy)-3-methoxy-18-methyl-13-((E)-4-methyl-pent-1-enyl)-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-ol

CAS号：862846-88-6

英文名：(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-diphenyl-silanyloxy)-3-methoxy-18-methyl-13-((E)-4-methyl-pent-1-enyl)-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-ol

分子式：C41H62O6Si

分子量：679.013

合成路线

2,4,6-trimethylbenzenesulfonic acid (2R,6S)-6-((R)-4-benzyloxy-2-methoxybutyl)-5,6-dihydro-2H-pyran-2-ylmethyl ester

2,4,6-trimethylbenzenesulfonic acid (2R,6S)-6-((R)-4-benzyloxy-2-methoxybutyl)-5,6-dihydro-2H-pyran-2-ylmethyl ester

(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-diphenyl-silanyloxy)-3-methoxy-18-methyl-13-((E)-4-methyl-pent-1-enyl)-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-ol

(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-diphenyl-silanyloxy)-3-methoxy-18-methyl-13-((E)-4-methyl-pent-1-enyl)-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-ol

(E)-(2R,3S)-3-(Dimethyl-phenyl-silanyl)-2-hydroxy-hex-4-enoic acid isopropyl ester

(E)-(2R,3S)-3-(Dimethyl-phenyl-silanyl)-2-hydroxy-hex-4-enoic acid isopropyl ester

(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-diphenyl-silanyloxy)-3-methoxy-18-methyl-13-((E)-4-methyl-pent-1-enyl)-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-ol

(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-diphenyl-silanyloxy)-3-methoxy-18-methyl-13-((E)-4-methyl-pent-1-enyl)-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-ol

(2R,3S,4E)-3-(dimethylphenylsilanyl)-2-hydroxyhex-4-enoic acid isopropyl ester

(2R,3S,4E)-3-(dimethylphenylsilanyl)-2-hydroxyhex-4-enoic acid isopropyl ester

(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-diphenyl-silanyloxy)-3-methoxy-18-methyl-13-((E)-4-methyl-pent-1-enyl)-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-ol

(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-diphenyl-silanyloxy)-3-methoxy-18-methyl-13-((E)-4-methyl-pent-1-enyl)-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-ol

上游原料

(E)-(2R,3S)-3-(Dimethyl-phenyl-silanyl)-2-hydroxy-hex-4-enoic acid isopropyl ester (2R,3S,4E)-3-(dimethylphenylsilanyl)-2-hydroxyhex-4-enoic acid isopropyl ester 2,4,6-trimethylbenzenesulfonic acid (2R,6S)-6-((R)-4-benzyloxy-2-methoxybutyl)-5,6-dihydro-2H-pyran-2-ylmethyl ester

下游产品

(1R,3S,5S,7S,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one