百科

2-{(2R,6S)-6-[(2S,4R,5R)-2-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-6-oxo-hexyl]-tetrahydro-pyran-2-yl}-2-methyl-propionic acid 2-trimethylsilanyl-ethyl ester

CAS号：863663-04-1

英文名：2-{(2R,6S)-6-[(2S,4R,5R)-2-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-6-oxo-hexyl]-tetrahydro-pyran-2-yl}-2-methyl-propionic acid 2-trimethylsilanyl-ethyl ester

分子式：C34H60O6Si2

分子量：621.008

合成路线

863659-96-5

2-Methyl-2-[(2R,6S)-6-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-propionic acid methyl ester

863663-04-1

2-{(2R,6S)-6-[(2S,4R,5R)-2-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-6-oxo-hexyl]-tetrahydro-pyran-2-yl}-2-methyl-propionic acid 2-trimethylsilanyl-ethyl ester

863662-20-8

methyl 2-[(2R,6S)-tetrahydro-6-(2-hydroxyethyl)-2H-pyran-2-yl]-2-methylpropanoate

863663-04-1

2-{(2R,6S)-6-[(2S,4R,5R)-2-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-6-oxo-hexyl]-tetrahydro-pyran-2-yl}-2-methyl-propionic acid 2-trimethylsilanyl-ethyl ester

863661-93-2

2-((2R,6S)-6-Carboxymethyl-tetrahydro-pyran-2-yl)-2-methyl-propionic acid methyl ester

863663-04-1

2-{(2R,6S)-6-[(2S,4R,5R)-2-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-6-oxo-hexyl]-tetrahydro-pyran-2-yl}-2-methyl-propionic acid 2-trimethylsilanyl-ethyl ester

863659-97-6

2-[(2R,6S)-6-((R)-2-Hydroxy-pent-4-enyl)-tetrahydro-pyran-2-yl]-2-methyl-propionic acid methyl ester

863663-04-1

2-{(2R,6S)-6-[(2S,4R,5R)-2-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-6-oxo-hexyl]-tetrahydro-pyran-2-yl}-2-methyl-propionic acid 2-trimethylsilanyl-ethyl ester

863662-27-5

2-[(2R,6S)-6-((R)-2-Benzyloxy-pent-4-enyl)-tetrahydro-pyran-2-yl]-2-methyl-propionic acid methyl ester

863663-04-1

2-{(2R,6S)-6-[(2S,4R,5R)-2-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-6-oxo-hexyl]-tetrahydro-pyran-2-yl}-2-methyl-propionic acid 2-trimethylsilanyl-ethyl ester

上游原料

methyl 2-[(2R,6S)-tetrahydro-6-(2-hydroxyethyl)-2H-pyran-2-yl]-2-methylpropanoate 2-Methyl-2-[(2R,6S)-6-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-propionic acid methyl ester 2-[(2R,6S)-6-((R)-2-Hydroxy-pent-4-enyl)-tetrahydro-pyran-2-yl]-2-methyl-propionic acid methyl ester 2-[(2R,6S)-6-((R)-2-Benzyloxy-pent-4-enyl)-tetrahydro-pyran-2-yl]-2-methyl-propionic acid methyl ester 2-((2R,6S)-6-Carboxymethyl-tetrahydro-pyran-2-yl)-2-methyl-propionic acid methyl ester

下游产品

2-[6-(2-benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-7-{6-[3-(2,2-dimethyl-4-oxo-4H-benzo[1,3]dioxin-5-yl)-propyl]-tetrahydro-pyran-2-yl}-5-methyl-hept-6-enyl)-tetrahydro-pyran-2-yl]-2-methyl-propionic acid 2-trimethylsilanyl-ethyl ester